Art

J-GLOBAL ID：200902145876449110   Reference number：02A0525925

Selective Synthesis, Characterization, and Configurational Flexibility of the Coordinatively Unsaturated Metal Center of Half-Sandwich Type Complexes with the Less-Hindered Hydrotris(3,5-dimethyl-4-X-1-pyrazolyl)borate Ligands [Tp^D(D = Me₂,X)M^II(κ²-O,O′-L)] (M = Ni, Co; L = NO₃, OAc; X = Me, H, Br).

束縛の少ないヒドロトリス(3,5-ジメチル-4-X-1-ピラゾリル)ボラート配位子を用いる半サンドイッチ型錯体[Tp^Me2,XM^II(κ²-O,O′-L)](M=Ni,Co;L=NO₃,OAc;X=Me,H,Br)の配位不飽和金属中心の選択的合成,キャラクタリゼーション,および立体配置柔軟性

Author (6)： HIKICHI S (Tokyo Inst. Technol., Yokohama) ,  SASAKURA Y (Tokyo Inst. Technol., Yokohama) ,  YOSHIZAWA M (Tokyo Inst. Technol., Yokohama) ,  OHZU Y (Tokyo Inst. Technol., Yokohama) ,  MOROOKA Y (Tokyo Inst. Technol., Yokohama) ,  AKITA M (Tokyo Inst. Technol., Yokohama)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 75  Issue： 6  Page： 1255-1262  Publication year： Jun. 15, 2002 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *nickel complex ,...

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JST classification (2)： Cobalt bnd nickel complexes  (CE01092Y) ,  Crystal structure of complex of iron-group elements  (BK09040I)

Substance index (6)： Acetic acid ,  Tris(3,4,5-trimethyl-1H-pyrazole-1-yl) boronanion ,  Tri(3,5-dimethyl-1H-pyrazole-1-yl) boronanion ,  Tris(3,5-dimethyl-4-bromo-1H-pyrazole-1-yl) boronanion ,  Acetonitrile ,  Methanol

Reference (50)：

• 1) a) S. Trofimenko, “Scorpionates—The Coordination Chemistry of Polypyrazolylborate Ligands,” Imperial College Press, London (1999).
•  b) S. Torofimenko, Chem. Rev., 93, 943 (1993).
• 2) N. Kitajima and W. B. Tolman, Prog. Inorg. Chem., 43, 419 (1995).
• 3) S. Hikichi, H. Komatsuzaki, M. Akita, and Y. Moro-oka, J. Am. Chem. Soc., 120, 4699 (1998).
• 4) Our recent report of dioxygen complexes chemistry (except Co complex; Ref. 3) based on Tp^iPr₂ and Tp^tBu,iPr ligands. V: a) M. Kosugi, S. Hikichi, M. Akita, and Y. Moro-oka, J. Chem. Soc., Dalton Trans., 1999, 1369.

Terms in the title (11)： 束縛 ,  ジメチル ,  ボラート ,  配位子 ,  サンドイッチ ,  錯体 ,  CO ,  Br ,  不飽和 ,  キャラクタリゼーション ,  立体配置