Art

J-GLOBAL ID：200902150054338019   Reference number：01A0640347

Orbital control of π-facial selectivity in Diels-Alder reactions of cyclopentadienes having C(=O)YR substituents at the 5-positions.

5-位にC(=O)YR置換基を有するシクロペンタジエン類のDiels-Alder反応におけるπ-面選択性の軌道による制御

Author (5)： ISHIDA M (Gifu Univ., GIfu, JPN) ,  SAKAMOTO M (Gifu Univ., GIfu, JPN) ,  HATTORI H (Gifu Univ., GIfu, JPN) ,  SHIMIZU M (Gifu Univ., GIfu, JPN) ,  INAGAKI S (Gifu Univ., GIfu, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 42  Issue： 20  Page： 3471-3474  Publication year： May. 14, 2001 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *Diels-Alder reaction ,...

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JST classification (2)： Cyclopentanes  (CF04040L) ,  Electronic structure of molecules  (BH05010Q)

Substance index (28)： 2,4-Cyclopentene-1-carboxylic acid ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carboxylic acid ,  1,3-Cyclopentadiene-5-carboxylic acid methyl ester ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carboxylic acid methyl ester ,  2,4-Cyclopentadiene-1-carboxylic acid phenyl ester ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carboxylic acid phenyl ester ,  2,4-Cyclopentadiene-1-carboxylic acid 4-methoxyphenyl ester ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carboxylic acid 4-methoxyphenyl ester ,  2,4-Cyclopentadiene-1-carboxamide ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-carboxamide ,  2,4-Cyclopentadiene-1-thiocarboxylic acid S-methyl ester ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-thiocarboxylic acid S-methyl ester ,  2,4-Cyclopentadiene-1-dithiocarboxylic acid methyl ester ,  1,2,3,4,5-Pentamethyl-2,4-cyclopentadiene-1-dithiocarboxylic acid methyl ester ,  N-Phenylmaleinimide ,  (2β,6β,10-syn)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid ,  (2β,6β,10-anti)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid ,  (2β,6β,10-syn)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid methyl ester ,  (2β,6β,10-anti)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid methyl ester ,  (2β,6β,10-syn)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid phenyl ester ,  (2β,6β,10-anti)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid phenyl ester ,  (2β,6β,10-syn)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid 4-methoxyphenyl ester ,  (2β,6β,10-anti)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxylic acid 4-methoxyphenyl ester ,  (2β,6β,10-syn)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxamide ,  (2β,6β,10-anti)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-carboxamide ,  (2β,6β,10-syn)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-thiocarboxylic acid S-methyl ester ,  (2β,6β,10-anti)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-thiocarboxylic acid S-methyl ester ,  (2β,6β,10-anti)-3,5-Dioxo-4-phenyl-1α,7α,8,9,10-pentamethyl-4-azatricyclo[5.2.1.0^2,6]decane-8-ene-10-dithiocarboxylic acid methyl ester

Terms in the title (5)： 置換基 ,  シクロペンタジエン類 ,  Diels-Alder反応 ,  面選択性 ,  軌道