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J-GLOBAL ID：200902162316012142   Reference number：01A0569633

Ruthenium-Catalyzed Dehydrogenative Silylation of Aryloxazolines with Hydrosilanes via C-H Bond Cleavage.

C-H結合開裂を経たヒドロシランによるアリールオキサゾリンのルテニウム触媒-脱水素シリル化

Author (5)： KAKIUCHI F (Osaka Univ., Osaka) ,  IGI K (Osaka Univ., Osaka) ,  MATSUMOTO M (Osaka Univ., Osaka) ,  CHATANI N (Osaka Univ., Osaka) ,  MURAI S (Osaka Univ., Osaka)
Material： Chemistry Letters  (Chem Lett)
Issue： 5  Page： 422-423  Publication year： May. 05, 2001 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： C-H bond ,...

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JST classification (3)： Oxazoles,isoxazoles  (CF07080Y) ,  Organosilicon compounds  (CF08030C) ,  Nobel metal catalysts  (CB06122I)

Substance index (33)： Triphenylphosphine ,  2-Phenyl-4,4-dimethyl-2-oxazoline ,  Triethylsilane ,  3,3-Dimethyl-1-butene ,  2-[2-(Triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  Phenyldimethylsilane ,  tert-Butyldimethylsilane ,  2-[2-(Phenyldimethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[2-(tert-Butyldimethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-o-Tolyl-4,4-dimethyl-2-oxazoline ,  2-(2-Fluorophenyl)-4,4-dimethyl-2-oxazoline ,  2-[2-(Trifluoromethyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[3-(Dimethylamino)phenyl]-4,4-dimethyl-2-oxazoline ,  2-(3-Methoxyphenyl)-4,4-dimethyl-2-oxazoline ,  2-(3-Methylphenyl)-4,4-dimethyl-2-oxazoline ,  2-(3-Fluorophenyl)-4,4-dimethyl-2-oxazoline ,  2-[3-(Trifluoromethyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-(4-Methoxyphenyl)-4,4-dimethyl-2-oxazoline ,  2-p-Tolyl-4,4-dimethyl-2-oxazoline ,  2-(4-Fluorophenyl)-4,4-dimethyl-2-oxazoline ,  2-[4-(Trifluoromethyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[2-Methyl-6-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[2-Fluoro-6-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[2-(Trifluoromethyl)-6-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[5-(Dimethylamino)-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[5-Methoxy-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[5-Methyl-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[5-Fluoro-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[5-(Trifluoromethyl)-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[4-Methoxy-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[4-Methyl-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[4-Fluoro-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline ,  2-[4-(Trifluoromethyl)-2-(triethylsilyl)phenyl]-4,4-dimethyl-2-oxazoline

Reference (18)：

• 1) L. Birkofer and O. Stuhl, in “The Chemistry of Organic Silicon Compounds,” ed. by S. Patai and Z. Rappoport, John Wiley & Sons, Inc., New York (1989), pp. 680–694.
• 2) W. A. Gustavson, P. S. Epstein, and M. D. Curtis, Organometallics, 1, 884 (1982).
• 3) K. Ezbiansky, P. I. Djurovich, M. LaForest, D. J. Sinning, R. Zayes, and D. H. Berry, Organometallics, 17, 1455 (1998).
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• 5) N. A. Williams, Y. Uchimaru, and M. Tanaka, J. Chem. Soc., Chem. Commun., 1995, 1129.

Terms in the title (6)： C-H結合 ,  開裂 ,  ヒドロシラン ,  ルテニウム触媒 ,  脱水素 ,  シリル化