Art

J-GLOBAL ID：200902171930859479   Reference number：02A0718169

Selective Preparation of Benzyltitanium Compounds by the Metalative Reppe Reaction. Its Application to the First Synthesis of Alcyopterosin A.

メタル化的Reppe反応によるベンジルチタン化合物の選択的調製 アルシオプテロシンAの最初の合成への応用

Author (5)： TANAKA R (Tokyo Inst. Technol., Kanagawa, JPN) ,  NAKANO Y (Tokyo Inst. Technol., Kanagawa, JPN) ,  SUZUKI D (Tokyo Inst. Technol., Kanagawa, JPN) ,  URABE H (Tokyo Inst. Technol., Kanagawa, JPN) ,  SATO F (Tokyo Inst. Technol., Kanagawa, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 124  Issue： 33  Page： 9682-9683  Publication year： Aug. 21, 2002 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (1)： Group 4 and group 5 organic compounds  (CF09054V)

Substance index (17)： (Trimethylsilyl)propiolic acid tert-butyl ester ,  1-Octyne ,  Titanium(IV)tetraisopropoxide ,  Isopropylmagnesium chloride ,  1,1-Diisopropoxy-2-(trimethylsilyl)-5-hexyl-1-titana(IV)cyclopenta-2,4-diene-3-carboxylic acid tert-butyl ester ,  Propargyl bromide ,  2-(Trimethylsilyl)-4-[bromodiisopropoxytitanio(IV)methyl]-5-hexylbenzoic acid tert-butyl ester ,  2-(Trimethylsilyl)-4-methyl-5-hexylbenzoic acid tert-butyl ester ,  2-(Trimethylsilyl)-4-[bromodiisopropoxytitanio(IV)methyl]-5-(3,7-dimethyl-6-octenyl)benzoic acid tert-butyl ester ,  1-Hexyl-2-(trimethylsilyl)-3-[bromodiisopropoxytitanio(IV)methyl]-5-[2-(benzyloxy)ethyl]benzene ,  2,2-Bis(benzyloxymethyl)-4-[bromodiisopropoxytitanio(IV)methyl]-6-methylindan-5-carboxylic acid ethyl ester ,  N,N-Diethyl-4-[bromodiisopropoxytitanio(IV)methyl]-6-hexylindan-5-carboxamide ,  N,N-Diethyl-2,2-bis(benzyloxymethyl)-4-[bromodiisopropoxytitanio(IV)methyl]-6-methylindan-5-carboxamide ,  4-[Bromodiisopropoxytitanio(IV)methyl]-5-(trimethylsilyl)-6-hexylindan ,  1,1-Diisopropoxy-6-hexyl-3,4-propano-1,2-dihydro-1-titana(IV)benzocyclobutene ,  2,2-Bis(benzyloxymethyl)-4,7-bis(trimethylsilyl)-5-[bromodiisopropoxytitanio(IV)methyl]indan ,  Alcyopterosin A

Terms in the title (6)： メタル化 ,  ベンジル ,  チタン化合物 ,  調製 ,  アルシオプテロシンA ,  応用