Art

J-GLOBAL ID：200902173747706453   Reference number：01A1036311

Common synthetic strategy for optically active cyclic terpenoids having a 1,1,5-trimethyl-trans-decalin nucleus: syntheses of (+)-acuminolide, (-)-spongianolide A, and (+)-scalarenedial.

1,1,5-トリメチル-trans-デカリン核を有する光学活性な環状テルペノイドを合成する共通の方法 (+)-アクミノリド,(-)-スポンギアノリドA及び(+)-スカラレンジアールの合成

Author (5)： FURUICHI N (Kwansei Gakuin Univ., Nishinomiya, JPN) ,  HATA T (Kwansei Gakuin Univ., Nishinomiya, JPN) ,  SOETJIPTO H (Kwansei Gakuin Univ., Nishinomiya, JPN) ,  KATO M (Kwansei Gakuin Univ., Nishinomiya, JPN) ,  KATSUMURA S (Kwansei Gakuin Univ., Nishinomiya, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 57  Issue： 40  Page： 8425-8442  Publication year： Oct. 01, 2001 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *tricyclic diterpene ,...
Semi thesaurus term： トリメチル-trans-デカリン骨格

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JST classification (2)： Diterpenes,sesterterpenes  (CF10023R) ,  Synthesis of drugs  (GV01030F)

Substance index (23)： (+)-Scalarenedial ,  (+)-Acuminolide ,  (-)-Spongianolide A ,  β-Cyclogeraniol ,  3-Oxo-5-(2,6,6-trimethyl-1-cyclohexenyl)valeric acid methyl ester ,  rac-(4aα^*)-2-Oxo-5,5,8aβ^*-trimethyldecalin-1β^*-carboxylic acid methyl ester ,  rac-3-Oxo-5-[(4aS^*,8aS^*)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalene-1-yl]pentanoic acid methyl ester ,  rac-(1R^*,4aS^*,4bR^*,8aR^*,10aS^*)-2-Oxo-4b,8,8-trimethyltetradecahydrophenanthrene-1-carboxylic acid methyl ester ,  rac-3-Oxo-5-[(4aR^*,4bS^*,8aS^*,10aR^*)-2,4b,8,8,10a-pentamethyl-3,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-1-yl]pentanoic acid methyl ester ,  rac-(9β^*,10α^*,13α^*,14β^*)-4,4,8α^*-Trimethyl-17-oxo-D-homo-5β^*-androstane-17aα^*-carboxylic acid methyl ester ,  (2R,3R)-2,3-Butanediol ,  1-O,4-O-Dibenzyl-L-threitol ,  (1S,4aS,8aS)-2-Oxo-5,5,8a-trimethyldecahydronaphthalene-1-methanol ,  (1R,4aβ)-1α-(Hydroxymethyl)-5,5,8aα-trimethyldecalin-2-one ,  (1R,4aβ,8aβ)-1α-(Hydroxymethyl)-4bα,8,8,10aα-tetramethyltetradecahydrophenanthrene-2-one ,  (1S,4aα,8aα)-1β-(Hydroxymethyl)-4bβ,8,8,10aβ-tetramethyltetradecahydrophenanthrene-2-one ,  (4aα)-2-Oxo-5,5,8aβ-trimethyldecalin-1β-carboxylic acid methyl ester ,  (4aβ)-2-Oxo-5,5,8aα-trimethyldecalin-1α-carboxylic acid methyl ester ,  (1S,4′S,4aR,4bS,5′S,8aS,10aR)-4b,8,8,10a-Tetramethyl-4′,5′-bis(hydroxymethyl)-3,4,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydrospiro[phenanthrene-2(1H),2′-[1,3]dioxolane]-1-carboxylic acid methyl ester ,  (1R,4′S,4aS,4bR,5′S,6aS,10aS,10bR,12aS)-4b,7,7,10a,12a-Pentamethyl-4′,5′-bis(hydroxymethyl)-3,4,4a,4b,5,6,6a,7,8,9,10,10a,10b,11,12,12a-hexadecahydrospiro[chrysene-2(1H),2′-[1,3]dioxolane]-1-carboxylic acid methyl ester ,  (4aβ,8aβ)-2-Oxo-4bα,8,8,10aα-tetramethyltetradecahydrophenanthrene-1α-carboxylic acid methyl ester ,  (2S,4aβ,8aβ)-2′,2′,4bα,8,8,10aα-Hexamethyldodecahydrospiro[phenanthrene-2(1H),4′-[1,3]dioxolane]-1α-carbaldehyde ,  (9α,10β,13β,14α)-4,4,8β-Trimethyl-17-oxo-D-homo-5α-androstane-17aβ-carboxylic acid methyl ester

Terms in the title (5)： trans-デカリン ,  核 ,  光学活性 ,  環状 ,  テルペノイド