Art

J-GLOBAL ID：200902178319317142   Reference number：02A0525934

Selective 3-O- and/or 6-O-Glycosidation of Unprotected O- and S-Glycosides Promoted by an Intramolecularly Coordinated Arylboronic Compound.

保護されていないO-およびS-グリコシドの選択的3-O-および/または6-O-グリコシド化の分子内配位アリールボロン酸化合物による促進

Author (5)： OSHIMA K (Nagaoka Univ. Technol., Niigata) ,  YAMAUCHI T (Nagaoka Univ. Technol., Niigata) ,  SHIMOMURA M (Nagaoka Univ. Technol., Niigata) ,  MIYAUCHI S (Nagaoka Univ. Technol., Niigata) ,  AOYAMA Y (Kyoto Univ., Kyoto)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 75  Issue： 6  Page： 1319-1324  Publication year： Jun. 15, 2002 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： glycoside ,...

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JST classification (3)： Polysaccharides  (CF10054P) ,  Polycondensation  (CG04050Z) ,  Magnetic resonance of organic molecules  (BH06073K)

Substance index (14)： 3,3,3′,3′-Tetramethyl-spiro[2-oxonia-1-bora(IV)indan-1,1′-[1]bora[2]oxaindan] ,  Methyl 3-O-(2-O,3-O,4-O,6-O-tetraacetyl-β-D-glucopyranosyl)-α-L-fucopyranoside ,  Methyl 3-O-(2-O,3-O,4-O,6-O-tetraacetyl-β-D-galactopyranosyl)-α-L-fucopyranoside ,  Methyl 3-O-[1,1-(3-O,4-O,6-O-triacetyl-β-D-mannopyranose-1-O,2-O-diyl)ethyl]-α-L-fucopyranoside ,  Methyl 3-O-[α,α-(3-O,4-O,6-O-tribenzoyl-β-D-mannopyranose-1-O,2-O-diyl)benzyl]-α-L-fucopyranoside ,  Methyl 6-O-(2-O,3-O,4-O,6-O-tetraacetyl-β-D-glucopyranosyl)-α-D-galactopyranoside ,  Methyl 3-O,6-O-bis(2-O,3-O,4-O,6-O-tetraacetyl-β-D-glucopyranosyl)-α-D-galactopyranoside ,  Methyl 3-O-(2-O,3-O,4-O,6-O-tetraacetyl-β-D-galactopyranosyl)-α-D-galactopyranoside ,  Methyl 3-O,6-O-bis(2-O,3-O,4-O,6-O-tetraacetyl-β-D-galactopyranosyl)-α-D-galactopyranoside ,  Methyl 3-O-(2-O,3-O,4-O,6-O-tetraacetyl-β-D-glucopyranosyl)-α-D-mannopyranoside ,  Methyl 3-O,6-O-bis(2-O,3-O,4-O,6-O-tetraacetyl-β-D-glucopyranosyl)-α-D-mannopyranoside ,  Methyl 3-O,6-O-bis(2-O,3-O,4-O,6-O-tetraacetyl-β-D-galactopyranosyl)-α-D-mannopyranoside ,  1-(4-Methylphenylthio)-3-O,6-O-bis(2-O,3-O,4-O,6-O-tetraacetyl-β-D-glucopyranosyl)-1-deoxy-α-D-mannopyranose ,  1-(4-Methylphenylthio)-3-O,6-O-bis(2-O,3-O,4-O,6-O-tetraacetyl-β-D-glucopyranosyl)-1-deoxy-α-D-galactopyranose

Reference (26)：

• 1) For acylation: a) M. A. Nashed and L. Anderson, Tetrahedron Lett., 1976, 3503.
•  b) T. Ogawa and M. Matsui, Tetrahedronn, 37, 2363 (1981).
•  c) Y. Tsuda, M. D. Haque, and K. Yoshimoto, Chem. Pharm. Bull., 31, 1612 (1983).
•  For alkylation: d) T. Ogawa and M. Matsui, Carbohydr. Res., 62, C1 (1978).
•  e) S. David, A. Thieffry, and A. Veyrières, J. Chem . Soc., Perkin Trans. 1, 1981, 1796.

Terms in the title (4)： グリコシド ,  グリコシド化 ,  アリールボロン酸 ,  促進