Art

J-GLOBAL ID：200902181137276301   Reference number：01A0151561

Design, Synthesis, and 1,3-Dipolar Cycloaddition of (5R)-[and (5S)]-5,6-Dihydro-5-phenyl-2H-1,4-oxazin-2-one N-Oxides as Chiral (E)-Geometry-Fixed α-Alkoxycarbonylnitrones.

キラルな(E)-配置固定化α-アルコキシカルボニルニトロンとしての(5R)-[および(5S)]-5,6-ジヒドロ-5-フェニル-2H-1,4-オキサジン-2-オンN-オキシドの設計,合成および1,3-双極性環状付加

Author (9)： TAMURA O (Kanazawa Univ., Kanazawa, JPN) ,  GOTANDA K (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  YOSHINO J (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  MORITA Y (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  TERASHIMA R (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  KIKUCHI M (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  YAMASHITA M (Kyoto Pharmaceutical Univ., Kyoto, JPN) ,  ISHIBASHI H (Kanazawa Univ., Kanazawa, JPN) ,  SAKAMOTO M (Meiji Pharmaceutical Univ., Tokyo, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 65  Issue： 25  Page： 8544-8551  Publication year： Dec. 15, 2000 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： stereospecific reaction ,...
Semi thesaurus term： bridged compound

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JST classification (2)： Oxazines  (CF07100X) ,  Synthesis of antibiotics  (GX04000Z)

Substance index (28)： Isobutene ,  Norbornene ,  Cyclopentene ,  (R)-2-Amino-2-phenylethanol ,  (S)-2-Amino-2-phenylethanol ,  (5R)-5-Phenylmorpholine-2-one 4-oxide ,  (5S)-5-Phenylmorpholine-2-one 4-oxide ,  Ethyl vinyl ether ,  tert-Butyl(allyloxy)dimethylsilane ,  1-Hexene ,  2,3-Dihydrofuran ,  Methylenecyclopentane ,  (2R,3aβ)-2β-Ethoxy-7β-phenylhexahydroisoxazolo[3,2-c][1,4]oxazine-4-one ,  (2R)-2β-[(tert-Butyldimethylsilyloxy)methyl]-7β-phenyl-3,3aβ,6,7-tetrahydroisoxazolo[3,2-c][1,4]oxazine-4(2H)-one ,  (2S)-2β-Butyl-7β-phenyl-3,3aβ,6,7-tetrahydroisoxazolo[3,2-c][1,4]oxazine-4(2H)-one ,  (3aS)-7β-Phenyl-2,3,3aα,6,7,8aα-hexahydro-1,5,8-trioxa-7a-azacyclopenta[a]indene-4(3bβH)-one ,  (3aR)-2,2-Dimethyl-7β-phenyl-3,3aβ,6,7-tetrahydroisoxazolo[3,2-c][1,4]oxazine-4(2H)-one ,  (3aR)-7β-Phenyl-3,3aβ,6,7-tetrahydrospiro[isoxazolo[3,2-c][1,4]oxazine-2(4H),1′-cyclopentane]-4-one ,  (4R)-4β-Phenyl-3,4,6aα,7,8,9,10,10aα-octahydro-7β,10β-methano[1,4]oxazino[4,3-b][1,2]benzisoxazole-1(10bβH)-one ,  (3aS)-7β-Phenyl-2,3,3aα,6,7,8aα-hexahydro-1H-5,8-dioxa-7a-azacyclopenta[a]indene-4(3bβH)-one ,  (3aR)-7α-Phenyl-2,3,3aβ,6,7,8aβ-hexahydro-1H-5,8-dioxa-7a-azacyclopenta[a]indene-4(3bαH)-one ,  N-[(3R)-2-Oxo-3,3aβ,4,5,6,6aβ-hexahydro-2H-cyclopenta[b]furan-3α-yl]-3,5-dinitrobenzamide ,  Uracil polyoxin C ,  (αS,1R)-α-Amino-2β,3β-dihydroxy-4α-(uracil-1-yl)cyclopentane-1α-acetic acid ,  (3S)-3β-(Benzyloxycarbonylamino)-3,3aα,4,6aα-tetrahydro-2H-cyclopenta[b]furan-2-one ,  (1R,4S,5R)-4-Hydroxy-2-oxabicyclo[3.3.0]oct-7-en-3-one ,  (3aR)-7α-Phenyl-3aβ,6,7,8aβ-tetrahydro-3H-5,8-dioxa-7a-azacyclopenta[a]indene-4(3bαH)-one ,  (3S)-3β-Amino-3,3aα,4,6aα-tetrahydro-2H-cyclopenta[b]furan-2-one

Terms in the title (7)： キラル ,  配置固定 ,  フェニル ,  オキサジン ,  N-オキシド ,  設計 ,  環状付加