Art

J-GLOBAL ID：200902193846139073   Reference number：00A0970613

Z-Selective Horner-Wadsworth-Emmons Reaction of Ethyl(Diarylphosphono)acetates Using Sodium Iodide and DBU.

よう化ナトリウムとDBUを用いた(ジアリールホスホノ)酢酸エチルのZ-選択的Horner-Wadsworth-Emmons反応

Author (5)： ANDO K (Univ. Ryukyus, Okinawa, JPN) ,  OISHI T (Tohoku Univ., Sendai, JPN) ,  HIRAMA M (Tohoku Univ., Sendai, JPN) ,  OHNO H (Kyoto Univ., Kyoto, JPN) ,  IBUKA T (Kyoto Univ., Kyoto, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 65  Issue： 15  Page： 4745-4749  Publication year： Jul. 28, 2000 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： stereospecific reaction ,...
Semi thesaurus term： Horner-Wadsworth-Emmons反応

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JST classification (2)： Organop phosphorus compounds  (CF08040N) ,  Aliphatic aldehydes  (CF03180F)

Substance index (30)： Octanal ,  Benzaldehyde ,  DBU ,  Ethyl (diphenoxyphosphinyl)acetate ,  Di(o-tolyloxy)phosphinylacetic acid ethyl ester ,  (Z)-4-Ethyl-2-octenoic acid ethyl ester ,  (Z)-Cyclohexaneacrylic acid ethyl ester ,  (Z)-2-Decenoic acid ethyl ester ,  2-Ethylhexanal ,  Cyclohexanecarbaldehyde ,  (E)-2-Hexenal ,  (S)-Boc-Leucinal ,  (S)-2-[(p-Tolylsulfonyl)amino]-4-methylpentanal ,  (S)-2-(tert-Butoxycarbonylamino)-3-methylbutanal ,  (S)-2-[(2,4,6-Trimethylphenylsulfonyl)amino]-3-methylbutanal ,  (S)-2-[(2,3,6-Trimethyl-4-methoxyphenylsulfonyl)amino]-3-methylbutanal ,  (2S,3S)-2-[(2,3,6-Trimethyl-4-methoxyphenylsulfonyl)amino]-3-methylpentanal ,  (2Z,4S)-4-[(tert-Butyloxycarbonyl)amino]-6-methyl-2-heptenoic acid ethyl ester ,  (2Z,4S)-4-[(p-Tolylsulfonyl)amino]-6-methyl-2-heptenoic acid ethyl ester ,  (2Z,4S)-4-(tert-Butyloxycarbonylamino)-5-methyl-2-hexenoic acid ethyl ester ,  (2Z,4S)-4-[(2,4,6-Trimethylphenylsulfonyl)amino]-5-methyl-2-hexenoic acid ethyl ester ,  (2Z,4S)-4-[(2,3,6-Trimethyl-4-methoxyphenylsulfonyl)amino]-5-methyl-2-hexenoic acid ethyl ester ,  (2Z,4S,5S)-4-[(2,3,6-Trimethyl-4-methoxyphenylsulfonyl)amino]-5-methyl-2-heptenoic acid ethyl ester ,  1,4-Dioxaspiro[4.5]decane-2β-carbaldehyde ,  (S)-2-(tert-Butyldimethylsilyloxy)-5-[(tert-butyloxycarbonyl)amino]pentanal ,  2-Hydroxy-3β-(tert-butyldimethylsilyloxy)piperidine-1-carboxylic acid tert-butyl ester ,  (S)-2-(tert-Butyldimethylsilyloxy)-5-[benzoyl(tert-butyloxycarbonyl)amino]pentanal ,  (Z)-3-(1,4-Dioxaspiro[4.5]decane-2β-yl)acrylic acid ethyl ester ,  (2Z,4S)-4-(tert-Butyldimethylsilyloxy)-7-[(tert-butyloxycarbonyl)amino]-2-heptenoic acid ethyl ester ,  (2Z,4S)-4-(tert-Butyldimethylsilyloxy)-7-[benzoyl(tert-butyloxycarbonyl)amino]-2-heptenoic acid ethyl ester

Terms in the title (4)： よう化ナトリウム ,  DBU ,  酢酸エチル ,  Horner-Wadsworth-Emmons反応