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J-GLOBAL ID：200902195185806364   Reference number：97A0903363

Enantiomeric Separation of Carboxylic Acids Having Chiral Centers Remote from the Carboxyl Group by Labelling with a Chiral Fluorescent Derivatization Reagent.

キラルな蛍光性誘導体化試薬を用いる標識によるカルボキシル基から離れたキラル中心を持つカルボン酸のエナンチオマ分離

Author (3)： AKASAKA K (Tohoku Univ., Sendai, JPN) ,  MEGURO H (Tohoku Fukushi Univ., Sendai, JPN) ,  OHRUI H (Tohoku Univ., Sendai, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 38  Issue： 39  Page： 6853-6856  Publication year： Sep. 29, 1997 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： aliphatic carboxylic acid ,...
Semi thesaurus term： anthracenes ,...

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JST classification (2)： Aliphatic carboxylic acids,peroxycarboxylic acids,thiocarboxylic acids  (CF03200E) ,  Chromatography,electrophoresis  (CC01050S)

Substance index (27)： (S)-2-Methylbutanoic acid ,  (S)-3-Methylvaleric acid ,  [S,(+)]-4-Methylhexanoic acid ,  [S,(+)]-5-Methylheptanoic acid ,  [S,(+)]-6-Methyloctanoic acid ,  rac-(R^*)-2-メチルペンタン酸 ,  rac-(R^*)-4-メチルオクタン酸 ,  rac-(R^*)-4-メチルノナン酸 ,  (R)-3-Hydroxyvaleric acid ,  D-4-Hydroxycapric acid ,  (R)-5-Hydroxynonanoic acid ,  (S)-2-Methylbutyric acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-2-Methylbutyric acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (S)-3-Methylpentanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-3-Methylpentanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (S)-4-Methylhexanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-4-Methylhexanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (S)-5-Methylheptanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-5-Methylheptanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (S)-6-Methyloctanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-6-Methyloctanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (S)-2-Methylpentanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-2-Methylpentanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (S)-4-Methyloctanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-4-Methyloctanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (S)-4-Methylnonanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester ,  (R)-4-Methylnonanoic acid (S)-2-[(1,3-dioxo-2,3-dihydro-1H-naphth[2,3-f]isoindol)-2-yl]propyl ester

Terms in the title (9)： キラル ,  蛍光性 ,  誘導体化 ,  試薬 ,  標識 ,  カルボキシル基 ,  キラル中心 ,  カルボン酸 ,  エナンチオマ分離