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J-GLOBAL ID：200902202692555493   Reference number：05A0863030

Thermal Isomerization at a C=N Double Bond: How Does the Mechanism Vary with the Substituent?

C=N二重結合における熱異性化 置換基によって機構は如何に変化するか?

Author (4)： YAMATAKA Hiroshi (Dep. of Chemistry, Rikkyo Univ.) ,  AMMAL Salai Cheettu (Dep. of Chemistry, Rikkyo Univ.) ,  ASANO Tsutomu (Dep. of Applied Chemistry, Fac. of Engineering, Oita Univ.) ,  OHGA Yasushi (Dep. of Applied Chemistry, Fac. of Engineering, Oita Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 78  Issue： 10  Page： 1851-1855 (J-STAGE)  Publication year： 2005 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *imine ,...

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JST classification (3)： Rearrangement reaction,isomerization  (CF02070E) ,  Aromatic monocyclic amine,imine,quaternary ammonium,immonium compounds  (CF05050D) ,  Configuration and conformation of molecules  (BH05022J)

Substance index (3)： N-(Hexafluoroisopropylidene)aniline ,  N-(4-Nitrobenzylidene)aniline ,  N,1-Diphenyl-2,2,2-trifluoroethanimine

Reference (16)：

• 1) W. G. Herkstroeter, J. Am. Chem. Soc., 95, 8686 (1973).
• 2) A. V. Prosyanik, S. V. Loban’, D. V. Fedoseenko, and V. I. Markov, Zh. Org. Khim., 21, 709 (1985).
• 3) A. V. Prosyanik and S. V. Loban’, Zh. Org. Khim., 21, 1045 (1985).
• 4) A. V. Prosyanik, N. Yu. Kol’tsov, and V. A. Romanchenko, Zh. Org. Khim., 22, 1474 (1986).
• 5) T. Asano, T. Okada, and W. G. Herkstroeter, J. Org. Chem., 54, 379 (1989).

Terms in the title (3)： 二重結合 ,  熱異性化 ,  置換基