Art

J-GLOBAL ID：200902203108090111   Reference number：08A1128035

Chiral Tetrakis(2-thienyl)methane Derivative: A Possible Precursor for Cryptochiral Tetraalkylmethanes

キラルテトラキス(2-チエニル)メタン誘導体 クリプトキラルテトラアルキルメタンへの前駆体の可能性

Author (11)： MATSUMOTO Kouzou (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  MIKI Kaori (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  KURATA Hiroyuki (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  RIKITAKE Nobuo (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  NEHIRA Tatsuo (Graduate School of Integrated Arts and Sciences, Hiroshima Univ.) ,  INAGAKI Takuya (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  PESCITELLI Gennaro (Dep. of Chemistry, Univ. of Pisa) ,  HIRAO Yasukazu (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  KAWASE Takeshi (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  ODA Masaji (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.) ,  KUBO Takashi (Dep. of Chemistry, Graduate School of Sci., Osaka Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 37  Issue： 12  Page： 1236-1237 (J-STAGE)  Publication year： 2008 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *chiral stationary phase ,  high performance liquid chromatography ,  chemical synthesis ,  precursor (substance) ,  optical isomerism ,  *sulfur heterocyclic compound ,  absolute configuration ,  Raney catalyst ,  nickel catalyst ,  catalytic reduction ,  column chromatography ,  Electrospray Ionization Mass Spectrometry ,  circular dichroism spectrum ,  ultraviolet and visible absorption spectrum ,  Raney nickel catalyst ,  chirality ,  *Thiophenes
Semi thesaurus term： chiral stationary phase ,  cryptochirality

JST classification (2)： Thiophenes  (CF07074D) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (6)： 1,1′,1′′,1′′′-[Methanetetrayltetra(1,6-hexanediyl)]tetra(2,5-dimethoxybenzene) ,  1,1′,1′′,1′′′-[Methanetetrayltetra(1,6-hexanediyl)]tetra(4-methoxybenzene) ,  2,2′,2′′,2′′′-Methanetetrayltetrakis[5-[2-(2,5-dimethoxyphenyl)ethenyl]thiophene] ,  2,2′,2′′,2′′′-Methanetetrayltetrakis[5-[2-(4-methoxyphenyl)ethenyl]thiophene] ,  5-[5-Acetyl-2-thienyl(5-benzoyl-2-thienyl)5-bromo-2-thienylmethyl]thiophene-2-carbonitrile ,  Tetra(6-phenylhexyl)methane

Reference (23)：

• 1) a) K. Mislow, P. Bickart, Isr. J. Chem. 1977, 15, 1.
•  b) K. Mislow, Collect. Czech. Chem. Commun. 2003, 68, 849.
• 2) a) H. Wynberg, G. L. Hekkert, J. P. M. Houbier, H. W. Bosch, J. Am. Chem. Soc. 1965, 87, 2635.
•  b) W. T. Hoeve, H. Wynberg, J. Org. Chem. 1980, 45, 2754.
• 3) T. Kawasaki, H. Tanaka, T. Tsutsumi, T. Kasahara, I. Sato, K. Soai, J. Am. Chem. Soc. 2006, 128, 6032.

Terms in the title (4)： メタン ,  誘導体 ,  前駆体 ,  可能性