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J-GLOBAL ID：200902211820917394   Reference number：03A0463290

Regioselectivity shift from β-(1→6)- to β-(1→3)-glycosylation of non-protected methyl β-D-galactopyranosides using the stannylene activation method.

スタンニレン活性化法を用いる非保護メチルβ-D-ガラクトピラノシド類のβ-(1→6)-からβ-(1→3)-グリコシル化への位置選択性の変化

Author (3)： KAJI E (Kitasato Univ., Tokyo, JPN) ,  SHIBAYAMA K (Kitasato Univ., Tokyo, JPN) ,  IN K (Kitasato Univ., Tokyo, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 44  Issue： 26  Page： 4881-4885  Publication year： Jun. 23, 2003 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *Glycosylation ,...

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JST classification (2)： Glycosides  (CF10057O) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (14)： 1-Bromo-1-deoxy-α-D-glucopyranose 2,3,4,6-tetrapivalate ,  2-O,3-O,4-O,6-O-Tetrabenzyl-α-D-glucopyranosyl chloride ,  2-O,3-O,4-O,6-O-Tetrapivaloyl-α-D-glucopyranose ,  Methyl α-D-galactopyranoside ,  Methyl β-D-galactopyranoside ,  Methyl 6-O-(2-O,3-O,4-O,6-O-tetrapivaloyl-β-D-glucopyranosyl)-α-D-galactopyranoside ,  Methyl 6-O-(2-O,3-O,4-O,6-O-tetrapivaloyl-β-D-glucopyranosyl)-β-D-galactopyranoside ,  Methyl 6-O-(2-O,3-O,4-O,6-O-tetrabenzyl-β-D-glucopyranosyl)-α-D-galactopyranoside ,  Methyl 6-O-(2-O,3-O,4-O,6-O-tetrabenzyl-β-D-glucopyranosyl)-β-D-galactopyranoside ,  Methyl 3-O-(2-O,3-O,4-O,6-O-tetrabenzyl-β-D-glucopyranosyl)-β-D-galactopyranoside ,  Methyl 3-O,4-O-(dibutylstannylene)-β-D-galactopyranoside ,  Methyl 6-O-(methoxydibutylstannyl)-β-D-galactopyranoside ,  1-O-Methyl-4-O-(fluorodibutylstannyl)-3-oxylato-3-deoxy-β-D-galactopyranose・tetrabutylammonium salt ,  1-O-Methyl-3-O-(fluorodibutylstannyl)-4-oxylato-4-deoxy-β-D-galactopyranose・tetrabutylammonium salt

Terms in the title (4)： 活性化法 ,  メチルβ-D-ガラクトピラノシド ,  グリコシル化 ,  位置選択性