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J-GLOBAL ID：200902217690618614   Reference number：07A1161690

Total synthesis of (-)-2-epi-lentiginosine by use of chiral 5-hydroxy-1,5-dihydropyrrol-2-one as a building block

構築ブロックとしてキラルな5-ヒドロキシ-1,5-ジヒドロピロール-2-オンを使用した(-)-2-epi-レンチギノシンの全合成

Author (7)： MURAMATSU Takayuki (Dep. of Molecular Sci., Fac. of Engineering, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu 432-8561, JPN) ,  YAMASHITA Sho (Dep. of Molecular Sci., Fac. of Engineering, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu 432-8561, JPN) ,  NAKAMURA Yumiko (Dep. of Molecular Sci., Fac. of Engineering, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu 432-8561, JPN) ,  SUZUKI Masahisa (Dep. of Molecular Sci., Fac. of Engineering, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu 432-8561, JPN) ,  MASE Nobuyuki (Dep. of Molecular Sci., Fac. of Engineering, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu 432-8561, JPN) ,  YODA Hidemi (Dep. of Molecular Sci., Fac. of Engineering, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu 432-8561, JPN) ,  TAKABE Kunihiko (Dep. of Molecular Sci., Fac. of Engineering, Shizuoka Univ., 3-5-1 Johoku, Hamamatsu 432-8561, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 48  Issue： 51  Page： 8956-8959  Publication year： Dec. 17, 2007 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： total synthesis ,...
Semi thesaurus term： dihydroxylation ,...

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JST classification (2)： Alkaloids  (CF10030D) ,  Applications of enzymes  (EB09100B)

Substance index (18)： (3aα,3bβ,8aα)-2,2-Dimethyloctahydro-2H-1,3-dioxa-7a-azacyclopenta[a]indene-8-one ,  (3aS)-2,2-Dimethyl-3aα,3bβ,4,7,8,8aα-hexahydro-2H-1,3-dioxa-7a-azacyclopenta[a]indene-8-one ,  (3aβ,6aβ)-2,2-Dimethyl-5,6β-diallyltetrahydro-5H-1,3-dioxolo[4,5-c]pyrrole-4-one ,  (3aβ,6aβ)-2,2-Dimethyl-5-(4-methoxybenzyl)-6β-(2-oxo-3,3-dimethylbutyl)tetrahydro-5H-1,3-dioxolo[4,5-c]pyrrole-4-one ,  (3aβ,6aβ)-2,2-Dimethyl-5-(4-methoxybenzyl)-6β-allyltetrahydro-5H-1,3-dioxolo[4,5-c]pyrrole-4-one ,  (2S,3S,4S)-1-(4-Methoxybenzyl)-3,4-(isopropylidenedioxy)-5-oxopyrrolidine-2-carbonitrile ,  (3aβ,6aβ)-2,2-Dimethyl-5-(4-methoxybenzyl)-6β-methoxytetrahydro-5H-1,3-dioxolo[4,5-c]pyrrole-4-one ,  (3aβ,6aβ)-2,2-Dimethyl-6β-allyltetrahydro-5H-1,3-dioxolo[4,5-c]pyrrole-4-one ,  (3S)-1-(4-Methoxybenzyl)-3β,4β-dihydroxy-5α-acetoxypyrrolidine-2-one ,  (3S,4S)-3,4-Dihydroxy-D-glutamic acid ,  (5R)-1-(4-Methoxybenzyl)-5β-acetoxy-3-pyrroline-2-one ,  1-(4-Methoxybenzyl)-5α-hydroxy-3-pyrroline-2-one ,  2-epi-Lentiginosine ,  AI-77B ,  rac-1-(4-Methoxybenzyl)-5α^*-hydroxy-3-pyrroline-2-one ,  Calyculin A ,  Calyculin B ,  Maleic acid anhydride

Terms in the title (5)： 構築 ,  キラル ,  EPI ,  レンチギノシン ,  全合成