Art

J-GLOBAL ID：200902223472876199   Reference number：08A0516755

A Bidirectional Tunnel-like Structure with a Rigid, Thick, and Chiral Aromatic Macrocycle Prepared by Self-complementary 6,6′-Substituted Binaphthyl Monomer

自己補足的6,6′-置換ビナフチルモノマにより調製した,柔軟性がなく厚みのあるキラル芳香族大環状構造を有する2方向トンネル状構造

Author (6)： KUMEDA Kazuhiro (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture & Technol.) ,  ONO Munetosi (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture & Technol.) ,  KAWAI Atsushi (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture & Technol.) ,  OIKE Hideaki (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture & Technol.) ,  NOGUCHI Keiichi (Instrumentation Analysis Center, Tokyo Univ. of Agriculture & Technol.) ,  YONEZAWA Noriyuki (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture & Technol.)
Material： Chemistry Letters  (Chem Lett)
Volume： 37  Issue： 6  Page： 660-661 (J-STAGE)  Publication year： 2008 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *macrocyclic compound ,  *polynuclear aromatic compound ,  optical activity ,  *crystal structure ,  chemical synthesis ,  X-Ray Diffraction ,  cyclization reaction ,  condensation reaction ,  asymmetric molecule ,  functionalization ,  dimerization ,  cavity ,  porous medium ,  steric conformation ,  crystal packing ,  chirality ,  tunnel structure

JST classification (2)： Aromatic monocyclic side chain ethers  (CF05080K) ,  Eight or more-membered heterocyclic compounds  (CF07120T)

Substance index (3)： 6,6′-[Carbonyl(1,4-phenyleneoxy)[1,1′-bi[2-methoxynaphthalene]-6,6′-diyl]carbonyl(1,4-phenyleneoxy)]-1,1′-bi[2-methoxynaphthalene] ,  6′,6′′-[Oxy(1,4-phenylenecarbonyl)]-6′′′,6′′′′-[oxy(1,4-phenylenecarbonyl)]-6′′′′′,6-[oxy(1,4-phenylenecarbonyl)]tris(1,1′-bi[2-methoxynaphthalene]) ,  2,2′-Dimethoxy-6′-(4-fluorobenzoyl)-1,1′-binaphthalene-6-ol

Reference (15)：

• 1) a) W. Zhang, J. S. Moore, Angew. Chem., Int. Ed. 2006, 45, 4416.
•  b) D. Zhao, J. S. Moore, Chem. Commun. 2003, 807.
•  c) D. Venkataraman, S. Lee, J. Zhang, J. S. Moore, Nature 1994, 371, 591.
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• 2) a) Y. Hosokawa, T. Kawase, M. Oda, Chem. Commun. 2001, 1948.

Terms in the title (10)： 自己 ,  補足 ,  置換 ,  調製 ,  厚み ,  キラル ,  芳香族 ,  環状構造 ,  2方向 ,  トンネル