Art

J-GLOBAL ID：200902223810207001   Reference number：07A0407245

Competitive thermal ene reaction and Diels-Alder reactions of 2-[N-(alk-2-enyl)benzylamino]-3-vinylpyrido[1,2-a]pyrimidin-4(4H)-ones

2-[N-(アルカ-2-エニル)ベンジルアミノ]-3-ビニルピリド[1,2-a]ピリミジン-4(4H)-オン類の競争的熱エン反応及びDiels-Alder反応

Author (6)： NOGUCHI Michihiko (Dep. of Applied Molecular Bioscience, Graduate School of Medicine, Yamaguchi Univ., Tokiwadai, Ube 755-8611, JPN) ,  SUNAGAWA Toshiya (Dep. of Applied Molecular Bioscience, Graduate School of Medicine, Yamaguchi Univ., Tokiwadai, Ube 755-8611, JPN) ,  AKAO Ryosuke (Dep. of Applied Molecular Bioscience, Graduate School of Medicine, Yamaguchi Univ., Tokiwadai, Ube 755-8611, JPN) ,  YAMADA Hisashi (Dep. of Applied Molecular Bioscience, Graduate School of Medicine, Yamaguchi Univ., Tokiwadai, Ube 755-8611, JPN) ,  YAMAMOTO Hidetoshi (Dep. of Advanced Materials Sci. and Engineering, Graduate School of Sci. and Engineering, Tokiwadai, Ube 755-8611, JPN) ,  KAKEHI Akikazu (Dep. of Chemistry and Material Engineering, Fac. of Engineering, Shinshu Univ., Wakasato, Nagano 380-8553, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 63  Issue： 21  Page： 4548-4557  Publication year： May. 21, 2007 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： nitrogen heterocyclic compound ,...
Semi thesaurus term： Pyrimidines ,...

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JST classification (4)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Alkenes  (CF03030T) ,  Structure effect on organic reaction  (CF02110Z) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (17)： (E)-3-[2-(Allylbenzylamino)-4-oxo-4H-pyrido[1,2-a]pyrimidine-3-yl]propenoic acid ethyl ester ,  (E)-3-[4-Oxo-2-[[(E)-3-phenyl-2-propenyl]benzylamino]-4H-pyrido[1,2-a]pyrimidine-3-yl]propenoic acid ethyl ester ,  (6R)-5-Oxo-10-benzyl-4a,5,6,7-tetrahydro-4a,10,11-triaza-10H-cyclohepta[b]naphthalene-6-acetic acid ethyl ester ,  (6R,7R)-5-Oxo-7-phenyl-10-benzyl-4a,5,6,7-tetrahydro-4a,10,11-triaza-10H-cyclohepta[b]naphthalene-6-acetic acid ethyl ester ,  (4R)-4β-Phenyl-6-benzyl-1,2,4,4aβ,5,6,12,12bβ-octahydro-3-oxa-6,7,11a-triazabenzo[a]anthracene-2,12-dione ,  (7aS)-6-Benzyl-14-oxo-6,7,7aα,8,13,13aα,14,14a-octahydro-5,6,14a-triazapentaphene-13α-carboxylic acid ethyl ester ,  2-[(6R)-5-Oxo-10-benzyl-4a,5,6,7-tetrahydro-4a,10,11-triaza-10H-cyclohepta[b]naphthalene-6-yl]malonic acid diethyl ester ,  2-[4-Oxo-2-(allylbenzylamino)-4H-pyrido[1,2-a]pyrimidine-3-ylmethylene]malonic acid diethyl ester ,  2-Cyano-3-[4-oxo-2-(allylbenzylamino)-4H-pyrido[1,2-a]pyrimidine-3-yl]propenoic acid ethyl ester ,  2-Ethoxy-6-benzyl-12-oxo-4,4aβ,5,6,11a,12,12bβ-heptahydro-3-oxa-6,7,11a-triazabenzo[a]anthracene-1-carbonitrile ,  6-Oxo-11-benzyl-7,8,11-trihydro-5-oxa-11-aza-6H-cyclohepta[a]naphthalene-7-acetic acid ethyl ester ,  3-[2-Oxo-4-(allylbenzylamino)-2H-1-benzopyran-3-yl]propenoic acid ethyl ester ,  (4aS)-3-Ethoxy-5-oxo-11-benzyl-1,4aα,5,11,12,12aα-hexahydro-2,6-dioxa-11-azachrysene-4-carbonitrile ,  1,3-Dimethyl-2,4-dioxo-9-benzyl-2,3,4,5,6,9-hexahydro-1H-pyrimido[4,5-b]azepine-5-acetic acid ,  3-[1,3-Dimethyl-2,4-dioxo-6-(allylbenzylamino)-1,2,3,4-tetrahydropyrimidine-5-yl]propenoic acid ethyl ester ,  2-Cyano-2-(1,3-dimethyl-2,4-dioxo-9-benzyl-2,3,4,5,6,9-hexahydro-1H-pyrimido[4,5-b]azepine-5-yl)acetic acid ethyl ester ,  (4aS)-3-Ethyl-5,7-dioxo-6,8-dimethyl-9-benzyl-1,4aα,5,6,7,8,9,10,10aα-nonahydro-2-oxa-6,8,9-triazaphenanthrene-4-carbonitrile

Terms in the title (4)： ピリミジン ,  競争 ,  エン反応 ,  Diels-Alder反応