Lewis acid-aldehyde-solvent interactions.  A computational approach for determining the critical amount of THF molecules necessary for achieving a high enantioselection in chiral oxazaborolidinone-promoted asymmetric aldol reactions.

FUJIYAMA R; GOH K; KIYOOKA S

Art

J-GLOBAL ID：200902224010718756 Reference number：05A0138819

Lewis acid-aldehyde-solvent interactions. A computational approach for determining the critical amount of THF molecules necessary for achieving a high enantioselection in chiral oxazaborolidinone-promoted asymmetric aldol reactions.

Lews酸-アルデヒド-溶媒相互作用キラルなオキサザボロリジノンにより促進される不斉アルドール反応において高エナンチオ選択性を達成するために必要なTHF分子の臨界量のコンピュータを利用した決定法

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Material：
Volume： 46 Issue： 7 Page： 1211-1215 Publication year： Feb. 14, 2005
JST Material Number： E0366A ISSN： 0040-4039 Document type： Article
Article type：短報 Country of issue： United Kingdom (GBR) Language： ENGLISH (EN)

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Aromatic monocyclic aldehydes , Addition reaction,elimination reaction , Electronic structure of molecules

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