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J-GLOBAL ID：200902228116353973   Reference number：06A1032553

A Convenient, Catalyst-free Cross-coupling Reaction of α-Sulfur-substituted Alkylstannanes with Acid Chlorides Leading to α-Sulfur-substituted Ketones

α-硫黄置換アルキルスタンナンと酸塩化物との便利で無触媒の交差カップリング反応によるα-硫黄置換ケトンの生成

Author (2)： KAGOSHIMA Hirotaka (Center for Instrumental Analysis, Ibaraki Univ.) ,  TAKAHASHI Naoshi (Center for Instrumental Analysis, Ibaraki Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 36  Issue： 1  Page： 14-15 (J-STAGE)  Publication year： 2007 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： stannanes ,...

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JST classification (2)： Aromatic monocyclic ketones  (CF05170I) ,  Organic Sn,Pb,Po compounds  (CF09040U)

Substance index (19)： Benzoyl chloride ,  4-Chlorobenzoic acid chloride ,  4-Methoxybenzoic acid chloride ,  Thiobenzoic acid S-[1-(tributylstannyl)butyl] ester ,  Dithiocarbonic acid O-ethyl S-[1-(tributylstannyl)butyl] ester ,  1-(Phenylthio)-1-(tributylstannyl)butane ,  [1-(Methylthio)butyl]tributylstannane ,  Thiobenzoic acid S-(1-benzoylbutyl) ester ,  Thioacetic acid S-(1-benzoylbutyl) ester ,  Dithiocarbonic acid O-ethyl S-(1-benzoylbutyl) ester ,  Diethyldithiocarbamic acid 1-benzoylbutyl ester ,  α-(Phenylthio)valerophenone ,  α-(Methylthio)valerophenone ,  Thiobenzoic acid S-(1-benzoyl-2-methylpropyl) ester ,  Thiobenzoic acid S-(α-benzoylbenzyl) ester ,  Thiobenzoic acid S-phenacyl ester ,  Thiobenzoic acid S-[1-(4-methoxybenzoyl)butyl] ester ,  Thiobenzoic acid S-[1-(4-chlorobenzoyl)butyl] ester ,  Thiobenzoic acid S-[(E)-1-propyl-2-oxo-4-phenyl-3-butenyl] ester

Reference (22)：

• 1) a) Cross-Coupling Reactions: A Practical Guide, ed. by N. Miyaura, Springer-Verlag, Berlin, 2002.
•  b) Metal-Catalyzed Cross-Coupling Reactions, 2nd ed., ed. by A. de Meijere, F. Diederich, Wiley-VCH, Weinheim, 2004.
•  c) A. C. Frisch, M. Beller, Angew. Chem., Int. Ed. 2005, 44, 674.
• 2) a) V. Ferina, V. Krishnamurthy, W. J. Scott, Org. React. 1997, 50, 1.
•  b) P. Espinet, A. M. Echavarren, Angew. Chem., Int. Ed. 2004, 43, 4704.

Terms in the title (8)： 硫黄 ,  置換アルキル ,  スタンナン ,  酸塩化物 ,  触媒 ,  交差カップリング反応 ,  置換 ,  ケトン