Art

J-GLOBAL ID：200902234133620098   Reference number：08A0005196

Platinum-catalyzed Generation of Silylenes from Hydrodisilanes and Their Addition to α,β-Unsaturated Ketones

ヒドロジシラン類からのシリレンの白金触媒による発生とそれらのα,β-不飽和ケトンへの付加

Author (2)： OKAMOTO Kazuhiro (Dep. of Chemistry, Graduate School of Sci., Kyoto Univ.) ,  HAYASHI Tamio (Dep. of Chemistry, Graduate School of Sci., Kyoto Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 37  Issue： 1  Page： 108-109 (J-STAGE)  Publication year： 2008 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *disilanes ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=08A0005196&from=J-GLOBAL&jstjournalNo=S0742A") }}

JST classification (2)： Catalytic reactions in general  (CB06080F) ,  Organosilicon compounds  (CF08030C)

Substance index (17)： 1,1,1,2,2-Pentamethyldisilane ,  4-Phenyl-3-buten-2-one ,  4,4-Dimethyl-2,5-diphenyl-3-oxa-4-silacyclopentene ,  1,1,1,2,2-Pentaphenyldisilane ,  1,1,2-Trimethyl-1,2-diphenyldisilane ,  1,3-Diphenyl-3-(trimethylsilyl)-1-propanone ,  1,3-Diphenyl-3-(methyldiphenylsilyl)-1-propanone ,  β-Phenyl-β-(phenyldimethylsilyl)propiophenone ,  4-(Methyldiphenylsilyl)-4-phenyl-2-butanone ,  2-[α-(Methyldiphenylsilyl)benzyl]tetralin-1-one ,  1,3-Diphenyl-3-(methyldiphenylsilyl)-1-butanone ,  1-[2α-(Methyldiphenylsilyl)cyclopentane-1α-yl]ethanone ,  1-[2α-(Methyldiphenylsilyl)cyclohexane-1α-yl]ethanone ,  1,5-Diphenyl-3-(methyldiphenylsilyl)-4-pentene-1-one ,  1,5-Diphenyl-5-(methyldiphenylsilyl)-1-pentene-3-one ,  Pivalic acid (Z)-1,3-diphenyl-3-(methyldiphenylsilyl)-1-propenyl ester ,  Pivalic acid (Z)-1-[2-(methyldiphenylsilyl)cyclohexylidene]ethyl ester

Reference (18)：

• 1) H. Ottosson, P. G. Steel, Chem.—Eur. J. 2006, 12, 1576.
• 2) a) M. Ishikawa, K. Nakagawa, M. Kumada, J. Organomet. Chem. 1977, 135, C45.
•  b) J. Heinicke, B. Gehrhus, J. Organomet. Chem. 1992, 423, 13.
•  c) J. Heinicke, S. Meinel, J. Organomet. Chem. 1998, 561, 121.
•  d) S. A. Calad, K. A. Woerpel, J. Am. Chem. Soc. 2005, 127, 2046.

Terms in the title (3)： シリレン ,  白金触媒 ,  不飽和ケトン