Art

J-GLOBAL ID：200902236869227698   Reference number：09A0071630

Enantioselective Synthesis of Silanol

シラノールのエナンチオ選択的合成

Author (5)： IGAWA Kazunobu (Kyushu Univ., Fukuoka, JPN) ,  TAKADA Junko (Tokyo Inst. of Technol., Tokyo, JPN) ,  SHIMONO Tomohiro (Tokyo Inst. of Technol., Tokyo, JPN) ,  TOMOOKA Katsuhiko (Kyushu Univ., Fukuoka, JPN) ,  TOMOOKA Katsuhiko (Tokyo Inst. of Technol., Tokyo, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 130  Issue： 48  Page： 16132-16133  Publication year： Dec. 03, 2008 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  silanols ,  *organosilicon compound ,  inorganic acid ester ,  nucleophilic substitution reaction ,  reaction mechanism ,  density functional method ,  silicon heterocyclic compound ,  oxygen heterocyclic compound ,  ring-opening reaction ,  potential energy surface ,  organolithium compound
Semi thesaurus term： alkoxysilane

JST classification (2)： Organosilicon compounds  (CF08030C) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (10)： Butyl lithium ,  1,2-[(Phenyl tert-butylsilylene)bis(oxymethylene)]benzene ,  3-Phenyl-3-methyl-1,5-dihydro-2,4,3-benzodioxasilepin ,  3-Cyclohexyl-3-methyl-1,5-dihydro-2,4,3-benzodioxasilepin ,  2-[[(R)-tert-Butylphenylbutylsilyl]oxymethyl]benzyl alcohol ,  2-[[(R)-tert-Butylmethylphenylsilyl]oxymethyl]benzyl alcohol ,  2-[[(S)-tert-Butylmethylcyclohexylsilyl]oxymethyl]benzyl alcohol ,  (R)-tert-Butylphenylbutylsilanol ,  (R)-tert-Butylmethylphenylsilanol ,  (S)-tert-Butylmethylcyclohexylsilanol

Terms in the title (2)： シラノール ,  エナンチオ選択的合成