Art

J-GLOBAL ID：200902238045578826   Reference number：09A0408049

USE OF DIKETOPIPERAZINES FOR DETERMINING ABSOLUTE CONFIGURATIONS OF α-SUBSTITUTED SERINES BY ¹H-NMR SPECTROSCOPY

¹H-NMR分光法によるα-置換セリン類の絶体配置決定のためのジケトピペラジンの利用

Author (6)： SANO Shigeki (Univ. Tokushima, Tokushima, JPN) ,  NAKAO Michiyasu (Univ. Tokushima, Tokushima, JPN) ,  TAKEYASU Masanori (Univ. Tokushima, Tokushima, JPN) ,  KITAIKE Syuji (Univ. Tokushima, Tokushima, JPN) ,  YOSHIOKA Yasuko (Univ. Tokushima, Tokushima, JPN) ,  NAGAO Yoshimitsu (Univ. Tokushima, Tokushima, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 79  Page： 781-789  Publication year： Apr. 01, 2009 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： lactam ,  *nitrogen heterocyclic compound ,  *amino acid ,  NMR ,  spectroscopy ,  diastereomer ,  absolute configuration ,  condensation reaction ,  hydrogenolysis ,  substituent effect ,  functional group protection ,  deprotection ,  optical activity ,  *Diketopiperazines

JST classification (3)： Nitrogen heterocycles in general  (CF07040G) ,  Physical analysis of organic compounds  (CC03034A) ,  Amino acids  (CF10070V)

Substance index (15)： Z-2-Benzyl-L-Ser-OH ,  Z-2-Methyl-L-Ser-OH ,  Z-2-Hexyl-L-Ser-OH ,  Z-2-Allyl-L-Ser-OH ,  L-Phenylalanine methyl hydrochloric acid ,  D-Phe-OMe・Hydrochloride ,  Z-2-Benzyl-L-Ser-L-Phe-OMe ,  (3S,6S)-3,6-Dibenzyl-3-(hydroxymethyl)piperazine-2,5-dione ,  (3S,6S)-3-Methyl-3-hydroxymethyl-6-benzyl-piperazine-2,5-dione ,  (6S)-3-Hexyl-3-(hydroxymethyl)-6-benzylpiperazine-2,5-dione ,  (6S)-3-Allyl-3-(hydroxymethyl)-6-benzylpiperazine-2,5-dione ,  (3S,6R)-3,6-Dibenzyl-3-(hydroxymethyl)piperazine-2,5-dione ,  (3S,6R)-3-Methyl-3-hydroxymethyl-6-benzyl-piperazine-2,5-dione ,  (6R)-3-Hexyl-3-(hydroxymethyl)-6-benzylpiperazine-2,5-dione ,  (6R)-3-Allyl-3-(hydroxymethyl)-6-benzylpiperazine-2,5-dione

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Terms in the title (6)： 1H-NMR ,  分光法 ,  置換 ,  セリン ,  絶体配置 ,  ジケトピペラジン