Art

J-GLOBAL ID：200902245775828131   Reference number：03A0772832

Total Synthesis and Absolute Configuration of Otteliones A and B, Novel and Potent Antitumor Agents from a Freshwater Plant.

淡水植物からの新しい強力な抗腫よう薬,オッテリオンA及びBの全合成と絶対配置

Author (3)： ARAKI H (Tokyo Inst. Technol., Yokohama, JPN) ,  INOUE M (Sagami Chemical Res. Center, Kanagawa, JPN) ,  KATOH T (Tokyo Inst. Technol., Yokohama, JPN)
Material： Organic Letters  (Org Lett)
Volume： 5  Issue： 21  Page： 3903-3906  Publication year： Oct. 16, 2003 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *alicyclic ketone ,...

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JST classification (2)： Indenes  (CF06030O) ,  Synthesis of drugs  (GV01030F)

Substance index (13)： rel-1β^*-Ethenyl-3α^*-(3-hydroxy-4-methoxybenzyl)-7-methylene-1,2,3,3aβ^*,7,7aβ^*-hexahydro-4H-indene-4-one ,  Ottelione B ,  (1S)-1β,4β-Methano-6β,7β-(isopropylidenebisoxy)-8α-(tert-butyldimethylsiloxy)-1,4,4aβ,5,6,7,8,8aβ-octahydronaphthalene-5-one ,  (1R,3aβ,7aβ,9S)-5β,6β-(Isopropylidenebisoxy)-7α-(tert-butyldimethylsiloxy)-9-hydroxy-4α,3α-(epoxymethano)hydrindane-1α-carbaldehyde ,  (αS,1R,3aβ,7aβ,9S)-α-[3-(Methoxymethoxy)-4-methoxyphenyl]-5β,6β-(isopropylidenebisoxy)-7α-(tert-butyldimethylsiloxy)-9-hydroxy-4α,3α-(epoxymethano)hydrindane-1α-methanol ,  (1R,3aα,7aα)-3β-[α-Hydroxy-3-(methoxymethoxy)-4-methoxybenzyl]-4β-(tert-butyldimethylsiloxy)-5α,6α-(isopropylidenebisoxy)-7β-hydroxyhydrindane-1α-carbaldehyde ,  (1R,3aα,7aα)-3β-[3-(Methoxymethoxy)-4-methoxybenzyl]-4β-(tert-butyldimethylsiloxy)-5α,6α-(isopropylidenebisoxy)-7β-hydroxyhydrindane-1α-methanol ,  (1R,3aα,7aα)-3β-[3-(Methoxymethoxy)-4-methoxybenzyl]-4β-(tert-butyldimethylsiloxy)-5α,6α-(isopropylidenebisoxy)-7-oxohydrindane-1α-carbaldehyde ,  (1R,3aα,7aα)-3β-[3-(Methoxymethoxy)-4-methoxybenzyl]-4β-(tert-butyldimethylsiloxy)-5α,6α-(isopropylidenebisoxy)-7-methylenehydrindane-1α-carbaldehyde ,  (1S)-1α-Vinyl-3β-(3-hydroxy-4-methoxybenzyl)-4β-(tert-butyldimethylsiloxy)-7-methylene-2,3,3aα,4,5,6,7,7aα-octahydro-1H-indene-5α,6α-diol ,  (1S)-1α-Vinyl-3β-(3-acetoxy-4-methoxybenzyl)-4β-(tert-butyldimethylsiloxy)-5α,6α-(oxycarbonothioyloxy)-7-methylene-2,3,3aα,4,5,6,7,7aα-octahydro-1H-indene ,  (1S)-1α-Vinyl-3β-[3-(dichloroacetoxy)-4-methoxybenzyl]-7-methylene-2,3,3aα,4,7,7aα-hexahydro-1H-indene-4β-ol ,  (1S)-1α-Vinyl-3β-[3-(dichloroacetoxy)-4-methoxybenzyl]-7-methylene-2,3,3aα,4,7,7aα-hexahydro-1H-indene-4-one

Terms in the title (5)： 淡水植物 ,  抗腫よう薬 ,  オッテリオンA ,  全合成 ,  絶対配置