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J-GLOBAL ID：200902255685077329   Reference number：03A0151552

Glochidionionosides A-D: Megastigmane Glucosides from Leaves of Glochidion zeylanicum (GAERTN.) A. JUSS.

グロキジオニオノシドA~D Glochidion zeylanicum (GAERTN.) A.JUSSの葉からのメガスチグマングルコシド類

Author (7)： OTSUKA H (Hiroshima Univ., Hiroshima, JPN) ,  KIJIMA H (Hiroshima Univ., Hiroshima, JPN) ,  HIRATA E (Univ. Ryukyus, Okinawa, JPN) ,  SHINZATO T (Univ. Ryukyus, Okinawa, JPN) ,  TAKUSHI A (Okinawa Prefectural Experimental Station of Forestry, Okinawa, JPN) ,  BANDO M (Otsuka Pharmaceutical Co., Ltd., Tokushima, JPN) ,  TAKEDA Y (Univ. Tokushima, Tokushima, JPN)
Material： Chemical and Pharmaceutical Bulletin  (Chemical & Pharmaceutical Bulletin)
Volume： 51  Issue： 3  Page： 286-290  Publication year： Mar. 01, 2003 
JST Material Number： G0504A  ISSN： 0009-2363  CODEN： CPBTAL  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *glucoside ,...
Semi thesaurus term： Glochidion zeylanicum

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JST classification (2)： Glycosides  (CF10057O) ,  Plant biochemistry  (EH01050J)

Substance index (16)： Icariside B₅ ,  Glochidionionoside A ,  (4S)-3-(Hydroxymethyl)-4α-[(1E,3S)-3-hydroxy-1-butenyl]-4-hydroxy-5,5-dimethyl-2-cyclohexene-1-one ,  (4S)-3-[[[(R)-2-Methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]methyl]-4α-[(1E,3S)-3-[[(R)-2-methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]-1-butenyl]-4-hydroxy-5,5-dimethyl-2-cyclohexene-1-one ,  (4S)-3-[[[(S)-2-Methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]methyl]-4α-[(1E,3S)-3-[[(S)-2-methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]-1-butenyl]-4-hydroxy-5,5-dimethyl-2-cyclohexene-1-one ,  GlochidionionosideB ,  (4R)-3-(Hydroxymethyl)-4α-[(S)-3-hydroxybutyl]-5,5-dimethyl-2-cyclohexene-1-one ,  (4R)-3-[[(R)-2-Phenyl-2-methoxy-3,3,3-trifluoropropionyl]oxymethyl]-4α-[(S)-3-[[(R)-2-phenyl-2-methoxy-3,3,3-trifluoropropionyl]oxy]butyl]-5,5-dimethyl-2-cyclohexene-1-one ,  (4R)-3-[[(S)-2-Phenyl-2-methoxy-3,3,3-trifluoropropionyl]oxymethyl]-4α-[(S)-3-[[(S)-2-phenyl-2-methoxy-3,3,3-trifluoropropionyl]oxy]butyl]-5,5-dimethyl-2-cyclohexene-1-one ,  GlochidionionosideC ,  (4R)-3-(Hydroxymethyl)-4α-[(1E,3S)-3-hydroxy-1-butenyl]-5,5-dimethyl-2-cyclohexene-1-one ,  (4R)-3-[[[(R)-2-Methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]methyl]-4α-[(1E,3S)-3-[[(R)-2-methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]-1-butenyl]-5,5-dimethyl-2-cyclohexene-1-one ,  (4R)-3-[[[(S)-2-Methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]methyl]-4α-[(1E,3S)-3-[[(S)-2-methoxy-2-phenyl-3,3,3-trifluoropropionyl]oxy]-1-butenyl]-5,5-dimethyl-2-cyclohexene-1-one ,  GlochidionionosideD ,  4-(2α,4α-Dihydroxy-2,6,6-trimethylcyclohexylidene)-3-butene-2-one ,  4-[2α-Hydroxy-4α-(4-bromobenzoyloxy)-2,6,6-trimethylcyclohexylidene]-3-butene-2-one

Reference (17)：

• 1) Otsuka H., Hirata E., Takushi A., Shinzato T., Takeda Y., Bando M., Kido M., Chem. Pharm. Bull., 48, 547—551 (2000).
• 2) Bhakuni D. S., Joshi P. P., Uprety H., Kapil R. S., Phytochemistry, 13, 2541—2543 (1974).
• 3) Pouset J. L., Poison J., Tetrahedron Lett., 1969, 1173—1174 (1969).
• 4) Galbraith M. N., Horn D. H. S., J. Chem. Soc. Chem. Commun., 1972, 113—114 (1972).
• 5) Miyase T., Ueno A., Takizawa H., Kobayashi H., Oguchi H., Chem. Pharm. Bull., 36, 2475—2484 (1988).

Terms in the title (1)： 葉