Art

J-GLOBAL ID：200902267045836841   Reference number：05A0224134

Enantioselective Morita-Baylis-Hillman (MBH) reaction promoted by a heterobimetallic complex with a Lewis base.

Lewis塩基とヘテロ二金属錯体によって促進されたエナンチオ選択的Morita-Baylis-Hillman(MBH)反応

Author (3)： MATSUI K (Osaka Univ., Osaka, JPN) ,  TAKIZAWA S (Osaka Univ., Osaka, JPN) ,  SASAI H (Osaka Univ., Osaka, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 46  Issue： 11  Page： 1943-1946  Publication year： Mar. 14, 2005 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...
Semi thesaurus term： 不斉錯体 ,...

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JST classification (2)： Stereochemistry of organic reaction  (CF02130V) ,  Cyclopentanes  (CF04040L)

Substance index (20)： 1,1'-Bi(2-naphthol) ,  2-Cyclopenten-1-one ,  3-Phenylpropanal ,  2-[(S)-1-Hydroxy-3-phenylpropyl]-2-cyclopentene-1-one ,  2-Cyclohexen-1-one ,  Propionaldehyde ,  Isobutyraldehyde ,  Pivalaldehyde ,  Benzaldehyde ,  Cyclopentanecarbaldehyde ,  Cyclohexanecarbaldehyde ,  2-[(S)-1-Hydroxy-3-phenylpropyl]-2-cyclohexene-1-one ,  2-[(S)-1-Hydroxypropyl]-2-cyclohexene-1-one ,  2-[(S)-1-Hydroxy-2-methylpropyl]-2-cyclohexene-1-one ,  2-[(S)-1-Hydroxy-2,2-dimethylpropyl]-2-cyclopentene-1-one ,  2-[(S)-α-Hydroxybenzyl]-2-cyclopentene-1-one ,  2-[(S)-α-Hydroxybenzyl]-2-cyclohexene-1-one ,  2-[(S)-Hydroxycyclopentylmethyl]-2-cyclohexene-1-one ,  2-[(S)-Hydroxycyclohexylmethyl]-2-cyclopentene-1-one ,  2-[(S)-Hydroxycyclohexylmethyl]-2-cyclohexene-1-one

Terms in the title (3)： Lewis塩基 ,  金属錯体 ,  促進