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J-GLOBAL ID：200902270731767636   Reference number：06A0450946

SYNTHESIS AND FLUORESCENCE OF 6-(4-DIMETHYLAMINOPHENYL)- AND 6-[2-(4-N,N-DISUBSTITUTED AMINOPHENYL)VINYL]-4-METHYLTHIO-2-OXO-2H-PYRAN-3-CARBONITRILES IN SOLUTION AND IN THE SOLID STATES

6-(4-ジメチルアミノフェニル)-および6-[2-(4-N,N-二置換アミノフェニル)ビニル]-4-メチルチオ-2-オキソ-2H-ピラン-3-カルボニトリル類の合成ならびに溶液および固体状態での蛍光

Author (8)： MIZUYAMA Naoko (Nagasaki Univ., Nagasaki, JPN) ,  MURAKAMI Yuka (Nagasaki Univ., Nagasaki, JPN) ,  NAGAOKA Junko (Nagasaki Univ., Nagasaki, JPN) ,  KOHRA Shinya (Nagasaki Univ., Nagasaki, JPN) ,  UEDA Kazuo (Nagasaki Univ., Nagasaki, JPN) ,  HIRAOKA Kyoko (Nagasaki Univ., Nagasaki, JPN) ,  SHIGEMITSU Yasuhiro (Technol. Center of Nagasaki, Nagasaki, JPN) ,  TOMINAGA Yoshinori (Nagasaki Univ., Nagasaki, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 68  Issue： 6  Page： 1105-1108  Publication year： Jun. 01, 2006 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (2)： Pyranes  (CF07092R) ,  Fluorescence and phoshorescence compounds and complex molecules  (BH06062I)

Substance index (10)： 3-Cyano-4-(methylthio)-6-[4-(dimethylamino)phenyl]-2H-pyran-2-one ,  2-Oxo-4-(methylthio)-6-[4-(dimethylamino)styryl]-2H-pyran-3-carbonitrile ,  2-Oxo-4-(methylthio)-6-[4-(diethylamino)styryl]-2H-pyran-3-carbonitrile ,  2-Oxo-4-(methylthio)-6-[4-(diphenylamino)styryl]-2H-pyran-3-carbonitrile ,  3-Cyano-4-(dimethylamino)-6-[4-(dimethylamino)phenyl]-2H-pyran-2-one ,  2-Oxo-4-pyrrolizino-6-[4-(dimethylamino)phenyl]-2H-pyran-3-carbonitrile ,  2-Oxo-4-morpholino-6-[4-(dimethylamino)phenyl]-2H-pyran-3-carbonitrile ,  2-Oxo-4-morpholino-6-[4-(dimethylamino)styryl]-2H-pyran-3-carbonitrile ,  [2-Oxo-3-cyano-6-[4-(dimethylamino)phenyl]-2H-pyran-4-yl]malonic acid dimethyl ester ,  [2-Oxo-3-cyano-6-[4-(dimethylamino)styryl]-2H-pyran-4-yl]malonic acid dimethyl ester

Reference (12)：

• a) C. W. Tang and S. A. Van Slyke, Appl. Phys. Lett., 1987, 51, 913. b) C. W. Tang, S. A. Van Slyke, and C. H. Chen,.1 Appl. Phy., 1989, 65, 3610. c) M. Matsuoka, J. Soc. Dyers and Colourists, 1989, 105, 167. d) K Shirai, A. Yanagisawa, H. Takahashi, K Fukunishi, and M. Matsuoka, Dyes and Pigments, 1998, 39, 49. e) K. Shirai, M. Matsuoka, and K. Fukunishi, Dyes and Pigments, 2000, 47, 107.
• a) J. H. Burroghed, Nature, 1990, 347, 539. b) M. A. Baldo, M. E. Thompson, and S. It Forrest, Nature, 2000, 403, 750.
• a) K. Hirano, S. Minakata, and M. Komatsu, Chem. Lett., 2001, 8. b) K. Hirano, S. Minakata, and M. Komatsu, Bull. Chem. Soc. Jpn., 2001, 74, 1567.
• a) Y. Tominaga, Y. Matsuda, and G. Kobayashi, Heterocycles, 1976, 4, 1493. b) Y. Tominaga, A. Ushirogouchi, Y. Matsuda, and G. Kobayashi, Heterocycles, 1977, 8, 193. c) Y. Tominaga, Y. Matsuda, and G. Kobayashi, Chem. Pharm. Bull., 1984, 32, 1665. d) Y. Tominaga, A. Ushirogouchi, Y. Matsuda, and G. Kobayashi, Chem. Pharm. Bull., 1984, 32, 3384. e) Y. Tominaga, A. Ushirogouchi, and Y. Matsuda, J. Heterocycl. Chem., 1987, 24, 1557. f) Y. Tominaga, J. Org. Synth. Chem., 1989, 47, 413.
• 3a: red prisms (MeOH-toluene). H-NMR (CDC13) 8 2.66 (3f1, s, SMe), 3.11 (6H, s, 2xNMe2), 6.47 (1H, s, 5-H), 6.69 (2H, d, J=9.0 Hz, 3‘, 4’-H), 7.75 (2H, d,.1=9.0 Hz, 2’, 61-H).

Terms in the title (7)： 置換アミノ ,  フェニル ,  2H-ピラン ,  カルボニトリル ,  溶液 ,  固体状態 ,  蛍光