Art

J-GLOBAL ID：200902271053515237   Reference number：04A0592297

Origin of the Endo/Exo Stereoselectivity and Syn/Anti Face-Selectivity in Diels-Alder Reactions, Determined by Transition State Energy Partitioning

遷移状態エネルギー分配により決定するDiels-Alder反応のEndo/Exo立体選択性およびSyn/Anti面選択性の起源

Author (5)： KIRI S (Kagoshima Univ., Kagoshima) ,  ODO Y (Kagoshima Univ., Kagoshima) ,  OMAR H I (Kagoshima Univ., Kagoshima) ,  SHIMO T (Kagoshima Univ., Kagoshima) ,  SOMEKAWA K (Kagoshima Univ., Kagoshima)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 77  Issue： 8  Page： 1499-1504  Publication year： Aug. 15, 2004 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Diels-Alder reaction ,...
Semi thesaurus term： bridged compound ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=04A0592297&from=J-GLOBAL&jstjournalNo=G0450A") }}

JST classification (3)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Configuration and conformation of molecules  (BH05022J) ,  Bridged bicyclic carbocyclic compounds  (CF06100Q)

Substance index (12)： Cyclopentadiene ,  Maleic acid anhydride ,  Acrylonitrile ,  5-Fluoro-1,3-cyclopentadiene ,  5-Methyl-1,3-cyclopentadiene ,  Endic anhydride ,  3β,5β-Etheno-1α,2α-cyclopentanedicarboxylic anhydride ,  (1S,1β,4S,4β)-3α-Cyanonorborna-5-ene ,  (1R,4S)-1α-Fluoro-4α-cyano-2α,5α-ethenocyclopentane ,  (1S,4S)-1β-Fluoro-4α-cyano-2α,5α-ethenocyclopentane ,  (1R,4S)-1α-Methyl-4α-cyano-2α,5α-ethenocyclopentane ,  (1S,4S)-1β-Methyl-4α-cyano-2α,5α-ethenocyclopentane

Reference (28)：

• 1) a) R. B. Woodward and R. Hoffman, Angew. Chem., Int. Ed. Engl., 8, 781 (1969).
•  b) W. Carruthers, “Cycloaddition Reactions in Organic Synthesis,” Pergamon Press, Oxford, Great Britain (1990).
• 2) F. Fringuelli and A. Taticchi, “Dienes in the Diels–Alder Reactions,” John Wiley & Sons, New York (1990).
• 3) A. Arrieta and F. P. Cossio, J. Org. Chem., 66, 6178 (2001).
• 4) M. Ishida, M. Sakamoto, H. Hattori, M. Shimizu, and S. Inagaki, Tetrahedron Lett., 42, 3471 (2001).

Terms in the title (6)： 遷移状態 ,  エネルギー分配 ,  Diels-Alder反応 ,  立体選択性 ,  面選択性 ,  起源