Art

J-GLOBAL ID：200902276810228730   Reference number：07A0450590

Total synthesis of leustroducsin B via a convergent route

収束合成によるロイストロズクシンBの全合成

Author (6)： MIYASHITA Kazuyuki (Graduate School of Pharmaceutical Sciences, Osaka Univ., 1-6 Yamadaoka, Suita, Osaka 565-0871, JPN) ,  MIYASHITA Kazuyuki (Fac. of Pharmacy, Osaka Ohtani Univ., 3-11-1 Nishikiori-Kita, Tondabayashi, Osaka 584-8540, JPN) ,  TSUNEMI Tomoyuki (Graduate School of Pharmaceutical Sciences, Osaka Univ., 1-6 Yamadaoka, Suita, Osaka 565-0871, JPN) ,  HOSOKAWA Takafumi (Graduate School of Pharmaceutical Sciences, Osaka Univ., 1-6 Yamadaoka, Suita, Osaka 565-0871, JPN) ,  IKEJIRI Masahiro (Graduate School of Pharmaceutical Sciences, Osaka Univ., 1-6 Yamadaoka, Suita, Osaka 565-0871, JPN) ,  IMANISHI Takeshi (Graduate School of Pharmaceutical Sciences, Osaka Univ., 1-6 Yamadaoka, Suita, Osaka 565-0871, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 48  Issue： 22  Page： 3829-3833  Publication year： May. 28, 2007 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： total synthesis ,...
Semi thesaurus term： Actinomycetes ,...

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JST classification (3)： Synthesis of antibiotics  (GX04000Z) ,  Addition reaction,elimination reaction  (CF02030M) ,  Inorganic acid esters of aliphatic alcohol and thiol  (CF03140N)

Substance index (12)： (E)-2-Penten-1-ol ,  (2S)-2β-[(3R,4R,6R)-3-[2-(Allyloxycarbonylamino)ethyl]-3,4,6-trihydroxy-10-[(1R)-3β-[[(S)-6-methyloctanoyl]oxy]cyclohexane-1β-yl]-1,7,9-decatrienyl]-3β-ethyl-6-oxo-3,6-dihydro-2H-pyran ,  (4R)-2-(4-Methoxyphenyl)-4α-[(1S)-1-ethyl-4-(4-methoxybenzyloxy)-2-butenyl]-1,3-dioxolane ,  3-Acryloyl-4β-benzyloxazolidine-2-one ,  3-Cyclohexene-1β-carboxylic acid ,  (S)-6-Methyloctanoic acid 3α-[2-(tributylstannyl)vinyl]cyclohexan-1α-yl ester ,  1,4-Dideoxy-1-(tert-butyldiphenylsiloxymethyl)-2-(benzoyloxymethyl)-4-[(S)-1-(tert-butyldimethylsiloxy)-2-(4-methoxybenzyloxy)ethyl]-D-erythritol ,  1,4-Dideoxy-1-(tert-butyldiphenylsiloxymethyl)-2-[(3S,4S,5Z)-3,7-dihydroxy-4-ethyl-1,5-heptadienyl]-4-[(S)-1-(tert-butyldimethylsiloxy)-2-hydroxyethyl]-D-erythritol ,  1,4-Dideoxy-1-(tert-butyldiphenylsiloxymethyl)-2-[2-[(2S)-3β-ethyl-6-oxo-3,6-dihydro-2H-pyran-2β-yl]ethenyl]-4-[(R)-1-(tert-butyldimethylsiloxy)-3-iodo-2-propenyl]-D-erythritol ,  2-[[(2R,3S)-2,6-Bis(4-methoxybenzyloxy)-3-ethyl-4-hexenyl]sulfonyl]benzothiazole ,  D-Malic acid ,  Leustroducsin B

Terms in the title (3)： 収束合成 ,  ロイストロズクシンB ,  全合成