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J-GLOBAL ID：200902280767824593   Reference number：05A0456734

A RuH₂(CO)(PPh₃)₃-Catalyzed Regioselective Arylation of Aromatic Ketones with Arylboronates via Carbon-Hydrogen Bond Cleavage

RuH₂(CO)(PPh₃)₃を触媒とした,アリールボロン酸エステルによる炭素-水素結合開裂を経る芳香族ケトンの位置特異的アリール化

Author (4)： KAKIUCHI Fumitoshi (Osaka Univ., Osaka, JPN) ,  MATSUURA Yusuke (Osaka Univ., Osaka, JPN) ,  KAN Shintaro (Osaka Univ., Osaka, JPN) ,  CHATANI Naoto (Osaka Univ., Osaka, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 127  Issue： 16  Page： 5936-5945  Publication year： Apr. 27, 2005 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *arylation ,...

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JST classification (3)： Aromatic monocyclic ketones  (CF05170I) ,  Organoboron compounds  (CF08020R) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (38)： 2'-Methylacetophenone ,  2-Phenyl-5,5-dimethyl-2-bora-1,3-dioxane ,  2-Acetyl-3-methylbiphenyl ,  1-(2-Methylphenyl)ethanol ,  Acetophenone ,  α-Methylpropiophenone ,  α,α-Dimethylpropiophenone ,  2′-(Trifluoromethyl)acetophenone ,  4'-Methoxypivalophenone ,  4′-Fluoropivalophenone ,  1-Acetylnaphthalene ,  2-Acetylbiphenyl ,  2′,6′-Diphenylacetophenone ,  2′-Isobutyryl-1,1′:3′,1′′-terbenzene ,  2′-Pivaloyl-1,1′:3′,1′′-terbenzene ,  2-Acetyl-3-(trifluoromethyl)biphenyl ,  2-Pivaloyl-5-methoxybiphenyl ,  2-Pivaloyl-5-fluorobiphenyl ,  1-Acetyl-2-phenylnaphthalene ,  2-Acetylnaphthalene ,  2-Pivaloylnaphthalene ,  Tetralin-1-one ,  Benzosuberone ,  2,2-Dimethyltetralin-1-one ,  1-Phenyl-2-acetylnaphthalene ,  2-Acetyl-3-phenylnaphthalene ,  1,3-Diphenyl-2-acetylnaphthalene ,  1-Phenyl-2-pivaloylnaphthalene ,  2-Pivaloyl-3-phenylnaphthalene ,  8-Phenyltetralin-1-one ,  4-Phenyl-6,7,8,9-tetrahydro-5H-benzocycloheptene-5-one ,  2,2-Dimethyl-8-phenyltetralin-1-one ,  2-(4-Methoxyphenyl)-5,5-dimethyl-2-bora-1,3-dioxane ,  2-[4-(Dimethylamino)phenyl]-5,5-dimethyl-1,3,2-dioxaborinane ,  2-(4-Fluorophenyl)-5,5-dimethyl-2-bora-1,3-dioxane ,  2-(2-Methylphenyl)-5,5-dimethyl-1,3,2-dioxaborinane ,  2-(1-Naphthyl)-5,5-dimethyl-1,3,2-dioxaborinane ,  2-(4-Trifluoromethylphenyl)-5,5-dimethyl-1,3,2-dioxaborinane

Terms in the title (9)： CO ,  触媒 ,  アリールボロン酸 ,  エステル ,  炭素 ,  水素 ,  結合開裂 ,  芳香族ケトン ,  アリール化