Art

J-GLOBAL ID：200902290621923889   Reference number：09A0117094

Kinetic resolution of allylic esters in palladium-catalyzed asymmetric allylic alkylations using C-N bond axially chiral aminophosphine ligands

キラルなアミノホスフィン配位子C-N結合補助剤を用いるパラジウム触媒による不斉アリル位アルキル化におけるアリル性エステル類の速度論的分割

Author (6)： MINO Takashi (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba Univ., 1-33, Yayoi-cho, Inage-ku ...) ,  WAKUI Kazuya (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba Univ., 1-33, Yayoi-cho, Inage-ku ...) ,  OISHI Shunsuke (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba Univ., 1-33, Yayoi-cho, Inage-ku ...) ,  HATTORI Youtaro (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba Univ., 1-33, Yayoi-cho, Inage-ku ...) ,  SAKAMOTO Masami (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba Univ., 1-33, Yayoi-cho, Inage-ku ...) ,  FUJITA Tsutomu (Dep. of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba Univ., 1-33, Yayoi-cho, Inage-ku ...)
Material： Tetrahedron: Asymmetry  (Tetrahedron Asym)
Volume： 19  Issue： 23  Page： 2711-2716  Publication year： Dec. 01, 2008 
JST Material Number： T0907A  ISSN： 0957-4166  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *organophosphorus compound ,  chiral ligand ,  asymmetric reaction ,  optical resolution ,  reagent ,  ligand ,  ligand effect ,  alkylation ,  allyl compound
Semi thesaurus term： kinetic resolution ,  chiral auxiliary

JST classification (3)： Organop phosphorus compounds  (CF08040N) ,  Stereochemistry of organic reaction  (CF02130V) ,  Other separation methods  (CC01060D)

Substance index (15)： Malonic acid dimethyl ester ,  Acetic acid allyl ,  (aS)-1-[2-(Diphenylphosphino)-6-(acetoxymethyl)phenyl]-1H-indole ,  (aR)-1-[2-(Diphenylphosphino)-6-(acetoxymethyl)phenyl]-1H-indole ,  (aS)-1-[2-(Diphenylphosphino)-6-methylphenyl]-1H-indole ,  (aR)-1-[2-(Diphenylphosphino)-6-methylphenyl]-1H-indole ,  (aS)-1-[2-(Diphenylphosphino)-6-(trifluoromethyl)phenyl]-1H-indole ,  (aR)-1-[2-(Diphenylphosphino)-6-(trifluoromethyl)phenyl]-1H-indole ,  (aS)-1-[2-(Diphenylphosphino)-1-naphthyl]-1H-indole ,  (aR)-1-[2-(Diphenylphosphino)-1-naphthyl]-1H-indole ,  rac-(R^*)-α-Styrylbenzenemethanol acetate ,  (R)-1,3-Diphenyl-3-acetoxy-1-propene ,  [(R)-α-Styrylbenzyl]malonic acid dimethyl ester ,  1-[6-Methoxy-2-(diphenylphosphino)phenyl]-2α-(trimethylsiloxymethyl)pyrrolidine ,  N-[2-(Diphenylphosphino)benzylidene]-2α-methoxymethyl-1-pyrrolidinamine

Terms in the title (9)： キラル ,  ホスフィン配位子 ,  C-N結合 ,  補助剤 ,  パラジウム触媒 ,  アリル位アルキル化 ,  アリル ,  エステル類 ,  速度論的分割