Art

J-GLOBAL ID：200902297176784460   Reference number：08A0863717

Supramolecular Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate Mediated by Capped γ-Cyclodextrins: Critical Control of Enantioselectivity by Cap Rigidity

キャップしたγ-シクロデキストリンによって媒介された2-アントラセンカルボキシラートの超分子的エナンチオ認識光環化二量化 キャップ剛性によるエナンチオ選択性のクリティカル制御

Author (3)： YANG Cheng (Osaka Univ., Suita, JPN) ,  MORI Tadashi (Osaka Univ., Suita, JPN) ,  INOUE Yoshihisa (Osaka Univ., Suita, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 73  Issue： 15  Page： 5786-5794  Publication year： Aug. 01, 2008 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical modification ,  *photocyclization ,  *dimerization ,  asymmetric synthesis ,  stereospecificity ,  supermolecule ,  clathrate compound ,  cap structure ,  bridged compound ,  dextrin ,  cyclodextrin
Semi thesaurus term： 環化二量化 ,  Anthracenes ,  bridged compound

JST classification (5)： Polysaccharides  (CF10054P) ,  Molecular compounds  (CE02000C) ,  Anthracenes  (CF06060V) ,  Photochemical reaction,radical reaction  (CF02090A) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (7)： γ-Cyclodextrin ,  2-Anthracenecarboxylic acid ,  9,9′-Cyclo-10,10′-bi[9,10-dihydroanthracene]-2,3′-dicarboxylic acid ,  10,10′-Cyclo-9,9′-bi(9,10-dihydroanthracene)-2,2′-dicarboxylic acid ,  1-O,4-[(6-O-Tosyl-4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)]-6-O-tosyl-4-deoxy-α-D-glucopyranose ,  1-O,4-[(4-Deoxy-α-D-glucopyranose-4,1-O-diyl)(6-O-tosyl-4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)]-6-O-tosyl-4-deoxy-α-D-glucopyranose ,  1-O,4-[(4-Deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)(4-deoxy-α-D-glucopyranose-4,1-O-diyl)]-6-O-tosyl-4-deoxy-α-D-glucopyranose

Terms in the title (6)： キャップ ,  γ-シクロデキストリン ,  分子 ,  光環化 ,  剛性 ,  エナンチオ選択性