Art

J-GLOBAL ID：201002205265022344   Reference number：10A0339903

Iron-Catalyzed Regio- and Stereoselective Substitution of γ,δ-Epoxy-α,β-unsaturated Esters and Amides with Grignard Reagents

γ,δ-エポキシ-α,β-不飽和エステルおよびアミドのGrignard試薬による鉄接触位置および立体選択的置換

Author (4)： HATA Takeshi (Tokyo Inst. of Technol., Kanagawa, JPN) ,  BANNAI Rie (Tokyo Inst. of Technol., Kanagawa, JPN) ,  OTSUKI Mamoru (Tokyo Inst. of Technol., Kanagawa, JPN) ,  URABE Hirokazu (Tokyo Inst. of Technol., Kanagawa, JPN)
Material： Organic Letters  (Org Lett)
Volume： 12  Issue： 5  Page： 1012-1014  Publication year： Mar. 05, 2010 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *Grignard reagent ,  *iron catalyst ,  regiospecific reaction ,  stereospecific reaction ,  unsaturated carboxylic acid ,  *carboxylate(ester) ,  *carboxamide ,  cyclic ether ,  iron chloride ,  substitution reaction
Semi thesaurus term： epoxide

JST classification (1)： Nitrogen derivatives of aliphatic carboxylic acids  (CF03220A)

Substance index (15)： N,N-Diethyl-3-methyloxirane-2-acrylamide ,  (4S,5S)-N,N-Diethyl-4-phenyl-5-hydroxy-2-hexeneamide ,  3-Methyloxirane-2-acrylic acid ethyl ester ,  (4S,5S)-4-Phenyl-5-hydroxy-2-hexenoic acid ethyl ester ,  (4S,5S)-4-(o-Methoxyphenyl)-5-hydroxy-2-hexenoic acid ethyl ester ,  5β-(o-Methoxyphenyl)-6α-methyltetrahydro-2H-pyran-2-one ,  (4R,5S)-4-Methyl-5-hydroxy-2-hexenoic acid ethyl ester ,  N,N-Diethyl-4-[(S)-1-hydroxyethyl]-2-hexene-5-yneamide ,  (4R,5S)-N,N-Diethyl-4-methyl-5-hydroxy-2-hexeneamide ,  (4R,5S)-N,N-Diethyl-4-methyl-5-hydroxy-2-octeneamide ,  (4R,5R)-N,N-Diethyl-4-methyl-5-hydroxy-2-undeceneamide ,  N,N-Diethyl-4,5-dimethyl-5-hydroxy-2-hexeneamide ,  N,N-Diethyl-4,4-dimethyl-5-hydroxy-2-hexeneamide ,  N,N-Diethyl-3-(3,4-dihydro-3β-methyl-1H-2-benzopyran-4β-yl)acrylamide ,  (S)-N,N-Diethyl-4-phenyl-2-penteneamide

Terms in the title (7)： 不飽和エステル ,  アミド ,  Grignard試薬 ,  鉄 ,  接触位置 ,  立体 ,  置換