Art
J-GLOBAL ID：201002212502760530   Reference number：10A0929241

Kinetic Evidence for Dihapto (η2) π-Aryl Participation in Acid-Catalyzed Ring Opening of Diarylhomobenzoquinone Epoxides

ジアリールホモベンゾキノンエポキシドの酸触媒開環反応におけるジハプト(η2)π-アリール関与の速度論的証拠
Author (4)：
ASAHARA Haruyasu

About ASAHARA Haruyasu

(Osaka Univ., Osaka, JPN)

About Osaka Univ., Osaka, JPN

, 
SAITO Kohta

About SAITO Kohta

(Osaka Univ., Osaka, JPN)

About Osaka Univ., Osaka, JPN

, 
IKUMA Naohiko

About IKUMA Naohiko

(Osaka Univ., Osaka, JPN)

About Osaka Univ., Osaka, JPN

, 
OSHIMA Takumi

About OSHIMA Takumi

(Osaka Univ., Osaka, JPN)

About Osaka Univ., Osaka, JPN


Material：
Journal of Organic Chemistry  (J Org Chem)

About Journal of Organic Chemistry


Volume： 75  Issue： 3  Page： 733-740  Publication year： Feb. 05, 2010 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)
Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
acid catalytic reaction

About acid catalytic reaction

, 
cyclic ether

About cyclic ether

, 
quinone

About quinone

, 
reaction kinetics

About reaction kinetics

, 
*ring-opening reaction

About ring-opening reaction

, 
alicyclic ketone

About alicyclic ketone

, 
spiro-compound

About spiro-compound

, 
*substituent effect

About substituent effect

, 
reaction mechanism

About reaction mechanism

, 
LUMO

About LUMO

, 
*transannular reaction

About transannular reaction

, 
Hammett rule

About Hammett rule

, 
rate constant

About rate constant

, 
*Benzoquinones

About Benzoquinones

, 
*Epoxy Compounds

About Epoxy Compounds


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
*epoxide

About epoxide


JST classification (2)：
JST classification
Category name(code) classified by JST.
Three-membered heterocyclic compounds 
(CF07050R)

About Three-membered heterocyclic compounds

,  Aromatic monocyclic phenols and polyphenols 
(CF05090V)

About Aromatic monocyclic phenols and polyphenols

Substance index (4)：
Substance index
Chemical Substance indexed to the Article.
1,4-Dimethyl-2,2-(3-oxo-1,4-pentadiene-1,5-diyl)-3-(4-chlorophenyl)-7-hydroxytricyclo[2.2.2.03,5]octane-6,8-dione

About 1,4-Dimethyl-2,2-(3-oxo-1,4-pentadiene-1,5-diyl)-3-(4-chlorophenyl)-7-hydroxytricyclo[2.2.2.03,5]octane-6,8-dione

, 
1,9-Dimethyl-4-chloro-8-(4-chlorophenyl)-12-hydroxytetracyclo[7.2.2.02,7.08,10]tridecane-2(7),3,5-triene-11,13-dione

About 1,9-Dimethyl-4-chloro-8-(4-chlorophenyl)-12-hydroxytetracyclo[7.2.2.02,7.08,10]tridecane-2(7),3,5-triene-11,13-dione

, 
2,5-Dimethyl-2,3-epoxy-5,6-[α-(4-chlorophenyl)-4-chlorobenzylidene]-1,4-cyclohexanedione

About 2,5-Dimethyl-2,3-epoxy-5,6-[α-(4-chlorophenyl)-4-chlorobenzylidene]-1,4-cyclohexanedione

, 
ANCA 1040

About ANCA 1040

Terms in the title (4)：
Terms in the title
Keywords automatically extracted from the title.
酸触媒

About 酸触媒

, 
開環反応

About 開環反応

, 
速度論

About 速度論

, 
証拠

About 証拠


Return to Previous Page

TOP

BOTTOM