Art

J-GLOBAL ID：201002222160274200   Reference number：10A0534446

Preparation of syn-Tertiary Homoallylic Alcohols Utilizing Allenyltitanocenes Generated by Reductive Titanation of γ-Trimethylsilylpropargylic Carbonates

炭酸γ-トリメチルシリルプロパルギルの還元的チタン化により生成したアレニルチタノセンを用いるsyn-第三ホモアリルアルコールの調製

Author (4)： YATSUMONJI Yasutaka (Tokyo Univ. Agriculture and Technol., Tokyo, JPN) ,  SUGITA Takenori (Tokyo Univ. Agriculture and Technol., Tokyo, JPN) ,  TSUBOUCHI Akira (Tokyo Univ. Agriculture and Technol., Tokyo, JPN) ,  TAKEDA Takeshi (Tokyo Univ. Agriculture and Technol., Tokyo, JPN)
Material： Organic Letters  (Org Lett)
Volume： 12  Issue： 9  Page： 1968-1971  Publication year： May. 07, 2010 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： metalation ,  inorganic acid ester ,  *titanium complex ,  *metallocene ,  *organotitanium compound ,  chemical synthesis ,  alcohol ,  *vinyl compound ,  *aliphatic alcohol ,  *unsaturated alcohol ,  allene compound ,  *organosilicon compound
Semi thesaurus term： *titanocene derivative ,  チタン化 ,  *homoallyl alcohols ,  tertiary alcohol ,  carbonic ester

JST classification (1)： Aliphatic alcohols  (CF03090H)

Substance index (15)： (2S,3R)-2-(1-Cyclohexenyl)-3-methyl-4-pentene-2-ol ,  (2S,3R)-2-(1-Cyclohexenyl)-3-methyl-5-(trimethylsilyl)-4-pentyne-2-ol ,  (2S,3R)-2-(4-Methoxyphenyl)-3-methyl-4-pentene-2-ol ,  (2S,3R)-2-(4-Methoxyphenyl)-3-methyl-5-(trimethylsilyl)-4-pentyne-2-ol ,  (2S,3R)-2-[4-(Trifluoromethyl)phenyl]-3-methyl-4-pentene-2-ol ,  (2S,3R)-2,5-Diphenyl-3-vinyl-2-pentanol ,  (2S,3R)-2-Phenyl-3-phenethyl-5-(trimethylsilyl)-4-pentyne-2-ol ,  (2S,3R)-2-Phenyl-3-methyl-4-pentene-2-ol ,  (3R,4R)-1-(Trimethylsilyl)-3-benzyl-4,6-dimethyl-5-heptene-1-yne-4-ol ,  (3R,4R)-1-Phenyl-3-methyl-4-isobutyl-1,5-hexadiene-3-ol ,  (3R,4R)-3-Phenethyl-4-methyl-1,5-undecadiene-4-ol ,  (3R,4R)-3-Benzyl-4,6-dimethyl-1,5-heptadiene-4-ol ,  1-Phenyl-3,4-dimethyl-6-(trimethylsilyl)-5-hexyne-3-ol ,  1-Phenyl-4-methyl-6-(trimethylsilyl)-5-hexyne-3-ol ,  Carbonic acid ethyl 1-methyl-3-(trimethylsilyl)propargyl ester

Terms in the title (5)： 炭酸 ,  還元 ,  チタン ,  ホモアリルアルコール ,  調製