Art

J-GLOBAL ID：201002247934413987   Reference number：10A0107369

AlCl₃-mediated Defluorinative Diarylhydroxylation Transformation of CF₃: Chemoselective Arylation of CF₃ and Chlorocarbonyl Groups Attached to Aromatic Rings

CF₃のAlCl₃が媒介する脱フッ素化ジアリールヒドロキシル化 CF₃の化学選択的アリール化及び芳香族環に結合したクロロカルボニル基

Author (3)： OKAMOTO Akiko (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture and Technol.) ,  KUMEDA Kazuhiro (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture and Technol.) ,  YONEZAWA Noriyuki (Dep. of Organic and Polymer Materials Chemistry, Tokyo Univ. of Agriculture and Technol.)
Material： Chemistry Letters  (Chem Lett)
Volume： 39  Issue： 2  Page： 124-125 (J-STAGE)  Publication year： 2010 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *arylation ,  defluorination ,  aluminum chloride ,  proton magnetic resonance ,  chemical synthesis ,  reaction mechanism ,  *aromatic fluorine compound ,  aliphatic fluorine compound ,  sulfonic acid ,  *hydroxylation
Semi thesaurus term： *hydroxylation

JST classification (2)： Aromatic monocyclic halogen compounds  (CF05030H) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (9)： Trifluoromethanesulfonic acid ,  α,α,α-Trifluoro-p-toluoyl chloride ,  4-Fluoro-4′-trifluoromethylbenzophenone ,  4-(α-Hydroxy-4,4′-difluorobenzhydryl)-4′-fluorobenzophenone ,  4-(α-Hydroxy-4,4′-dichlorobenzhydryl)-4′-chlorobenzophenone ,  4-(α-Hydroxy-4,4′-dibromobenzhydryl)-4′-bromobenzophenone ,  4-(α-Hydroxy-4,4′-diiodobenzhydryl)-4′-iodobenzophenone ,  4-(α-Hydroxy-4,4′-difluorobenzhydryl)benzoic acid ,  Tri(4-fluorophenyl)methanol

Reference (25)：

• 1) Fluorine-Containing Synthons, ed. by V. A. Soloshonok, American Chemical Society, Washington, DC, 2005, Vol. 911.
• 2) H. Amii, K. Uneyama, Chem. Rev. 2009, 109, 2119.
• 3) a) W. X. Gu, M. R. Haneline, C. Douvris, O. V. Ozerov, J. Am. Chem. Soc. 2009, 131, 11203.
•  b) J. Terao, M. Nakamura, N. Kambe, Chem. Commun. 2009, 6011.
• 4) a) K. Fuchibe, Y. Ohshima, K. Mitomi, T. Akiyama, J. Fluorine Chem. 2007, 128, 1158.

Terms in the title (6)： AlCl3 ,  脱フッ素化 ,  化学 ,  アリール化 ,  芳香族環 ,  カルボニル基