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J-GLOBAL ID：201002267808834609   Reference number：10A0064784

Enantioselective Intramolecular Oxidative Aminocarbonylation of Alkenylureas Catalyzed by Palladium-Spiro Bis(isoxazoline) Complexes

パラジウム-スピロビス(イソオキサゾリン)錯体触媒によるアルケニル尿素のエナンチオ選択的な分子内酸化的アミノカルボニル化

Author (7)： TSUJIHARA Tetsuya (Iwate Medical Univ., Iwate, JPN) ,  SHINOHARA Toshio (Osaka Univ., Osaka, JPN) ,  TAKENAKA Kazuhiro (Osaka Univ., Osaka, JPN) ,  TAKIZAWA Shinobu (Osaka Univ., Osaka, JPN) ,  ONITSUKA Kiyotaka (Osaka Univ., Osaka, JPN) ,  HATANAKA Minoru (Iwate Medical Univ., Iwate, JPN) ,  SASAI Hiroaki (Osaka Univ., Osaka, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 74  Issue： 24  Page： 9274-9279  Publication year： Dec. 18, 2009 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *urea compound ,  olefin compound ,  carbonylation ,  *spiro-compound ,  sulfamide ,  palladium complex ,  palladium catalyst ,  optical isomerism ,  oxygen heterocyclic compound ,  catalytic reaction ,  nitrogen heterocyclic compound ,  *ligand effect ,  reaction mechanism ,  *asymmetric synthesis ,  chiral ligand ,  Carbon Monoxide ,  quinone ,  alicyclic compound ,  diene ,  *aminocarbonylation ,  Pyrimidines ,  Complex Catalysts ,  *isoxazoline derivative
Semi thesaurus term： *isoxazolines

JST classification (2)： Oxazoles,isoxazoles  (CF07080Y) ,  Aliphatic ureas,carbamic acids,guanidines  (CF03240W)

Substance index (13)： 3,3,3′,3′-Tetraisopropyl-3,3′,3aβ,3′aβ,4,4′,5,5′-octahydro-6,6′-spirobi[6H-cyclopenta[c]isoxazole] ,  1,3-Dioxo-2-(4-methylphenylsulfonyl)octahydropyrrolo[1,2-c]pyrimidine-6,6-dicarboxylic acid diethyl ester ,  1-(2,2-Dimethyl-4-pentenyl)-3-tosylurea ,  1-Tosyl-4,4-dimethylpyrrolidine-2-acetic acid methyl ester ,  2,2′-Bis(5,5-diethyl-2-isoxazoline-3-yl)-1,1′-binaphthalene ,  2,2-Dimethyl-5-benzyl-6-oxo-4-thia-3a,5-diaza-2,3,3a,5,6,7,7a-heptahydro-1H-indene 4,4-dioxide ,  2-(2-Methylphenylsulfonyl)-6,6-dimethyloctahydropyrrolo[1,2-c]pyrimidine-1,3-dione ,  2-Tosyloctahydropyrrolo[1,2-c]pyrimidine-1,3-dione ,  2-Tosyl-4a,5-dihydrospiro[pyrrolo[1,2-c]pyrimidine-6(7H),1′-cyclohexane]-1,3(2H,4H)-dione ,  3-Tosyl-8,8-dimethyl-1,3-diazabicyclo[4.3.0]nonane-2,4-dione ,  N-Tosyl-2,2-dimethyl-4-pentenylamine ,  2,2-Dimethyl-4-pentenylamino(benzylamino) sulfone ,  p-Benzoquinone

Terms in the title (6)： パラジウム ,  イソオキサゾリン ,  錯体触媒 ,  尿素 ,  酸化 ,  アミノカルボニル化