Art

J-GLOBAL ID：201102211185324614   Reference number：11A1835909

Solvent-induced selectivity switching: intermolecular allylsilylation, arylsilylation, and silylation of alkynes over montmorillonite catalyst

溶媒誘起選択性スイッチング モントモリロナイト触媒によるアルキンの分子間アリルシリル化,アリールシリル化,およびシリル化

Author (5)： MOTOKURA Ken (Dep. of Environmental Chemistry and Engineering, Tokyo Inst. of Technol., 4259 Nagatsuta-cho, Midori-ku, Yokohama ...) ,  MATSUNAGA Shigekazu (Dep. of Environmental Chemistry and Engineering, Tokyo Inst. of Technol., 4259 Nagatsuta-cho, Midori-ku, Yokohama ...) ,  MIYAJI Akimitsu (Dep. of Environmental Chemistry and Engineering, Tokyo Inst. of Technol., 4259 Nagatsuta-cho, Midori-ku, Yokohama ...) ,  YASHIMA Tatsuaki (Advanced Res. Inst. for the Sciences and Humanities, Nihon Univ., 12-5 Gobancho, Chiyoda-ku, Tokyo 102-8251, JPN) ,  BABA Toshihide (Dep. of Environmental Chemistry and Engineering, Tokyo Inst. of Technol., 4259 Nagatsuta-cho, Midori-ku, Yokohama ...)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 52  Issue： 50  Page： 6687-6692  Publication year： Dec. 14, 2011 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  catalytic reaction ,  heterogeneous reaction ,  *montmorillonite ,  ion exchange ,  *silylation ,  acetylenic compound ,  catalytic activity ,  olefin compound ,  *solvent effect ,  silanes ,  organosilicon compound ,  reaction mechanism ,  aromatic hydrocarbon
Semi thesaurus term： proton exchange

JST classification (3)： Catalytic reactions(heterogeneous system)  (CB06100E) ,  Other effects on organic reaction  (CF02120K) ,  Organosilicon compounds  (CF08030C)

Substance index (13)： Allyltrimethylsilane ,  Phenylethynyltriethylsilane ,  1-(Trimethylsilyl)-1-octyne ,  Trimethyl(2-phenyl-1,4-pentadienyl)silane ,  Trimethyl(2-phenyl-3-methyl-1,4-pentadienyl)silane ,  Trimethyl(2-phenyl-4-methyl-1,4-pentadienyl)silane ,  3-(Trimethylsilyl)propargylbenzene ,  Trimethyl(4-chlorophenylethynyl)silane ,  Trimethyl(p-tolylethynyl)silane ,  Trimethyl(β-phenyl-2,4,6-trimethylstyryl)silane ,  Trimethyl(phenylethynyl)silane ,  Trimethyl[2-(4-chlorophenyl)-1,4-pentadienyl]silane ,  Phenylacetylene

Terms in the title (9)： 溶媒 ,  誘起 ,  選択性 ,  スイッチング ,  モントモリロナイト ,  触媒 ,  アルキン ,  アリル ,  シリル化