Art

J-GLOBAL ID：201102254109808247   Reference number：11A1431763

Kinetic Studies of the Ni-catalyzed Cross-coupling of Alkyl Halides and a Tosylate with Butyl Grignard Reagent in the Presence of 1,3-Butadiene

1,3-ブタジエン存在下におけるアルキルハライドとトシラートのブチルGrignard試薬とのNi触媒交差カップリングの速度論的研究

Author (6)： IWASAKI Takanori (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Univ.) ,  TSUMURA Asako (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Univ.) ,  OMORI Takehiro (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Univ.) ,  KUNIYASU Hitoshi (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Univ.) ,  TERAO Jun (Dep. of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto Univ.) ,  KAMBE Nobuaki (Dep. of Applied Chemistry, Graduate School of Engineering, Osaka Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 40  Issue： 9  Page： 1024-1026 (J-STAGE)  Publication year： 2011 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *cross coupling reaction ,  *Grignard reagent ,  *aliphatic halogen compound ,  *nickel catalyst ,  reaction rate ,  bromide ,  nickel compound ,  order of reaction ,  concentration dependence ,  rate-limiting ,  chemical equilibrium ,  aggregation ,  activation energy ,  enthalpy ,  Entropy ,  reaction mechanism ,  reaction intermediate ,  *sulfonic acid ,  addition reaction ,  alkadiene
Semi thesaurus term： nickel bromide ,  rate determining step

JST classification (4)： Addition reaction,elimination reaction  (CF02030M) ,  Catalytic reactions(homogeneous system)  (CB06090Q) ,  Group 1 and group 2 organic compounds  (CF09020Y) ,  Aliphatic halogen compounds  (CF03050P)

Substance index (6)： Butadiene ,  p-Toluenesulfonic acid heptyl ester ,  Undecane ,  p-Toluenesulfonic acid anion ,  1-Bromononane ,  1-Iodohexane

Reference (30)：

• 1) a) J. Magano, J. R. Dunetz, Chem. Rev. 2011, 111, 2177.
•  b) C. Torborg, M. Beller, Adv. Synth. Catal. 2009, 351, 3027.
• 2) a) M. R. Netherton, G. C. Fu, Adv. Synth. Catal. 2004, 346, 1525.
•  b) A. C. Frisch, M. Beller, Angew. Chem., Int. Ed. 2005, 44, 674.
•  c) M. R. Netherton, G. C. Fu, Palladium in Organic Synthesis in Topics in Organometallic Chemistry, ed. by J. Tsuji, Springer-Verlag, Berlin, 2005, Vol. 14, pp. 85–108. doi:10.1007/b104127.

Terms in the title (8)： ブタジエン ,  トシラート ,  Grignard試薬 ,  Ni ,  触媒 ,  交差カップリング ,  速度論 ,  研究