Art

J-GLOBAL ID：201102277368209696   Reference number：11A0963458

The reaction of acetal-type protective groups in combination with TMSOTf and 2,2′-bipyridyl; mild and chemoselective deprotection and direct conversion to other protective groups

TMSOTfと2,2′-ビピリジルとの組み合わせたアセタール型保護基の反応 ; 温和かつ化学選択的脱保護ならびに他の保護基への直接変換

Author (5)： FUJIOKA Hiromichi (Graduate School of Pharmaceutical Sciences, Osaka Univ., Suita, Osaka 565-0871, JPN) ,  MINAMITSUJI Yutaka (Graduate School of Pharmaceutical Sciences, Osaka Univ., Suita, Osaka 565-0871, JPN) ,  KUBO Ozora (Graduate School of Pharmaceutical Sciences, Osaka Univ., Suita, Osaka 565-0871, JPN) ,  SENAMI Kento (Graduate School of Pharmaceutical Sciences, Osaka Univ., Suita, Osaka 565-0871, JPN) ,  MAEGAWA Tomohiro (Graduate School of Pharmaceutical Sciences, Osaka Univ., Suita, Osaka 565-0871, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 67  Issue： 16  Page： 2949-2960  Publication year： Apr. 22, 2011 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *deprotection ,  nitrogen heterocyclic compound ,  hydrolysis ,  pyridinium ,  *reaction intermediate ,  *etherification ,  *functional group protection ,  *ether ,  sulfonate ,  *organosilicon compound ,  silanols ,  aliphatic alcohol

JST classification (1)： Pyridines  (CF07095Q)

Substance index (16)： 12-[(Benzyloxy)methoxy]dodecanoic acid methyl ester ,  12-Hydroxydodecaneoic acid tert-butyl ester ,  Methyl 12-hydroxydodecanoate ,  1-(Methoxymethoxy)decane ,  1-(Methoxymethoxy)-12-(trityloxy)dodecane ,  1-[(Allyloxy)methoxy]decane ,  1-Decanol ,  1-Phenyl-3-(methoxymethoxy)propene ,  2,2'-Dipyridyl ,  2-(Methoxymethoxy)decane ,  2-Methyl-4-phenyl-2-butanol ,  9-(Methoxymethoxy)nonane-1-amine ,  N-(9-Hydroxynonyl)benzamide ,  TESOTf ,  Trimethylsilyl trifluoromethanesulfonate ,  Benzoic acid 12-(methoxymethoxy)dodecyl ester

Terms in the title (5)： TMSOTf ,  アセタール ,  保護基 ,  化学 ,  直接変換