Art

J-GLOBAL ID：201102295003784070   Reference number：11A1242042

Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates

ベンジルボロン酸類の簡便合成のためのジボリルメタンの化学選択的Suzukiカップリング

Author (4)： ENDO Kohei (Waseda Inst. Advanced Study, Tokyo, JPN) ,  ENDO Kohei (JST-PRESTO, Saitama, JPN) ,  OHKUBO Takahiro (Waseda Univ., Tokyo, JPN) ,  SHIBATA Takanori (Waseda Univ., Tokyo, JPN)
Material： Organic Letters  (Org Lett)
Volume： 13  Issue： 13  Page： 3368-3371  Publication year： Jul. 01, 2011 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： chemical reaction ,  *Suzuki reaction ,  palladium catalyst ,  aromatic bromine compound ,  steric hindrance ,  density functional method ,  reaction intermediate ,  LUMO ,  potassium hydroxide ,  *organic boron acid
Semi thesaurus term： B3LYP ,  *Suzuki-Miyaura coupling ,  *boronic ester ,  *chemoselective reaction

JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  Organoboron compounds  (CF08020R)

Substance index (24)： 2,2′-Methylenebis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) ,  2,2′-Ethylidenebis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) ,  1-Bromo-4-methoxybenzene ,  4-Bromotoluene ,  2-(4-Methoxybenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(α-Methyl-4-methoxybenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(4-Methylbenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(4-Fluorobenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  1-Bromo-3-methoxybenzene ,  3-Bromotoluene ,  2-(3-Methoxybenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(3-Methylbenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  1-Bromo-2-methoxybenzene ,  1-Bromo-2-methylbenzene ,  2-(2-Methoxybenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-(2-Methylbenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-Bromobiphenyl ,  2-(2-Biphenylylmethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  1,3-Dimethoxy-2-bromobenzene ,  2-(2,6-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  1,3-Dimethyl-2-bromobenzene ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-m-xylene ,  2-(4-Bromophenethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2,2′-[Methylene(1,4-phenylene)ethylene]bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

Terms in the title (5)： ベンジル ,  ボロン酸類 ,  簡便 ,  化学 ,  Suzukiカップリング