Art

J-GLOBAL ID：201202298530660989   Reference number：12A0231099

Reactions of (polypyrazolylborato)(benzonitrile)rutheniums with terminal alkynes: Reactivity changeover by triethylamine toward arylalkyne polymerization or formation of (arylmethyl)(carbonyl) complexes

(ポリピラゾリルボラート)(ベンゾニトリル)ルテニウムと末端アルキンの反応 アリールアルキンの重合もしくは(アリールメチル)(カルボニル)錯体生成に向けたトリエチルアミンによる反応性の切換え

Author (12)： ONISHI Masayoshi (Dep. of Applied Chemistry, Fac. of Engineering, Nagasaki Univ., Nagasaki 852-8521, JPN) ,  ARIKAWA Yasuhiro (Graduate School of Sci. and Technol., Nagasaki Univ., Nagasaki 852-8521, JPN) ,  YAMAGUCHI Mamoru (Graduate School of Sci. and Technol., Nagasaki Univ., Nagasaki 852-8521, JPN) ,  NAGANO Tomoe (Dep. of Applied Chemistry, Fac. of Engineering, Nagasaki Univ., Nagasaki 852-8521, JPN) ,  INOUE Takayuki (Dep. of Applied Chemistry, Fac. of Engineering, Nagasaki Univ., Nagasaki 852-8521, JPN) ,  TERASOBA Atsunobu (Dep. of Applied Chemistry, Fac. of Engineering, Nagasaki Univ., Nagasaki 852-8521, JPN) ,  MATSUO Suguru (Graduate School of Sci. and Technol., Nagasaki Univ., Nagasaki 852-8521, JPN) ,  NAKAGAWA Maki (Dep. of Applied Chemistry, Fac. of Engineering, Nagasaki Univ., Nagasaki 852-8521, JPN) ,  KAWANO Hiroyuki (Div. of Liberal Arts, Kogakuin Univ., Hachioji, 192-0015, JPN) ,  NAGAOKA Junko (Dep. of Applied Chemistry, Fac. of Engineering, Nagasaki Univ., Nagasaki 852-8521, JPN) ,  UMAKOSHI Keisuke (Dep. of Applied Chemistry, Fac. of Engineering, Nagasaki Univ., Nagasaki 852-8521, JPN) ,  FURUKAWA Mutsuhisa (Graduate School of Sci. and Technol., Nagasaki Univ., Nagasaki 852-8521, JPN)
Material： Journal of Organometallic Chemistry  (J Organomet Chem)
Volume： 700  Page： 135-141  Publication year： Mar. 01, 2012 
JST Material Number： B0412C  ISSN： 0022-328X  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Thesaurus term： *ruthenium complex ,  *alkyne ,  chloro complex ,  ruthenium catalyst ,  catalytic reaction ,  Polymerization ,  *organoruthenium compound ,  *carbene complex ,  reaction intermediate ,  carbonyl complex ,  reactivity ,  reaction mechanism ,  alkylbenzene ,  aliphatic amine ,  tertiary amine ,  aromatic hydrocarbon ,  acetylenic compound ,  aromatic nitrile ,  *vinylidene complex ,  Complex Catalysts

JST classification (3)： Alkynes  (CF03040E) ,  Organic platinum group compound  (CF09058L) ,  Platinum family element complexes  (CE01100E)

Substance index (6)： p-Xylene ,  Tetrakis(4-bromo-1H-pyrazole-1-yl) boron(IV) ,  Triethylamine ,  Toluene ,  Phenylacetylene ,  Benzonitrile

Terms in the title (9)： ベンゾニトリル ,  ルテニウム ,  末端アルキン ,  重合 ,  カルボニル ,  錯体生成 ,  トリエチルアミン ,  反応性 ,  切換え