Art

J-GLOBAL ID：201302240706527600   Reference number：13A1926782

Chemistry of Propargyl Compounds Activated by Sulfur Functional Groups-Development of Methodology for the Synthesis of Heterocyles Triggered by Functionalizations

硫黄で活性化されたプロパルギル化合物の化学-官能基導入に誘発されるヘテロ環合成法の開発について-

Author (3)： YOSHIMATSU MITSUHIRO (岐阜大 教育) ,  TANABE GENZO (近畿大 薬) ,  MURAOKA OSAMU (近畿大 薬)
Material： 有機合成化学協会誌  (Journal of Synthetic Organic Chemistry, Japan)
Volume： 71  Issue： 12  Page： 1282-1293  Publication year： Dec. 01, 2013 
JST Material Number： F0383A  ISSN： 0037-9980  CODEN： YGKKAE  Document type： Article
Article type： 解説  Country of issue： Japan (JPN)  Language： JAPANESE (JA)

Thesaurus term： alkynylation ,  *acetylenic compound ,  *heterocyclic compound ,  cyclization reaction ,  diyne ,  chemical bond ,  selenium ,  addition reaction ,  regiospecific reaction ,  Lewis acid catalyst
Semi thesaurus term： propargylation ,  *heterocyclic compound ,  regiospecific reaction ,  functional group ,  bond formation ,  organic synthetic reaction

JST classification (1)： Heterocyclic compounds in general  (CF07010Z)

Substance index (15)： 2-Methyl-4-(2-thenyl)-5-(phenylthio)thiazole ,  2-Methyl-4-(phenylthio)-5-(2-thenyl)thiazole ,  2-Methyl-4-(4-fluorobenzyl)-5-(phenylthio)thiazole ,  2-Phenyl-4-(4-methoxybenzyl)-5-(phenylthio)thiazole ,  2-Phenyl-4-benzyl-5-(phenylthio)thiazole ,  2-Phenyl-4-(4-fluorobenzyl)-5-(phenylthio)thiazole ,  2-Phenyl-4-(1-naphthylmethyl)-5-(phenylthio)thiazole ,  2-Phenyl-4-(4-methoxybenzyl)selenazole ,  2-Methyl-4-(4-methoxybenzyl)selenazole ,  2-Phenyl-4-[(phenylthio)methylene]spiro[2-thiazoline-5,1′-cyclohexane] ,  6-Phenyl-2-(phenylthio)spiro[4H-1,3-thiazine-4,1′-cyclohexane] ,  O-[[4-[(Phenylthio)methyl]-5-(4-methoxyphenyl)-3-furyl]methyl]-N-(tert-butyloxycarbonyl)-L-tyrosine methyl ester ,  O-[[4-[(Phenylthio)methyl]-5-(4-fluorophenyl)-3-furyl]methyl]-N-(tert-butyloxycarbonyl)-L-tyrosine methyl ester ,  O-[[4-[(Phenylthio)methyl]-5-(2-thienyl)-3-furyl]methyl]-N-(tert-butyloxycarbonyl)-L-tyrosine methyl ester ,  O-[[4-[(Phenylthio)methyl]-5-(1-naphthyl)-3-furyl]methyl]-N-(tert-butyloxycarbonyl)-L-tyrosine methyl ester

Reference (84)：

• 1) (a) B. Witulski, C. Alayrac, “Science of Synthesis” ed. by A. de Meijere, Georg Thieme Verlag, Stuttgart, New York, Vol. 24, 933 (2006)
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• (c) Z. F. Al-Rashid, R. P. Hsung, Org. Lett., 10, 661 (2008)
• 3) (a) A. S. K. Hashmi, M. Rudolph, J. Huck, W. Frey, J. W. Bats, M. Hamzic, Angew. Chem. Int. Ed., 48, 5848 (2009)

Terms in the title (9)： 硫黄 ,  活性化 ,  プロパルギル ,  化学 ,  官能基 ,  誘発 ,  ヘテロ環 ,  合成法 ,  開発