Stereoselective synthesis of CF<sub>3</sub>-substituted trans- and cis-enediynes via carbocupration or hydrostannation reactions of CF<sub>3</sub>-containing diyne

KONNO Tsutomu; KISHI Misato; ISHIHARA Takashi; YAMADA Shigeyuki

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J-GLOBAL ID：201402211939220316 Reference number：14A0357656

Stereoselective synthesis of CF₃-substituted trans- and cis-enediynes via carbocupration or hydrostannation reactions of CF₃-containing diyne

CF₃-含有ジインのカルボクプレーションまたはヒドロスタンニル化を経るCF₃-置換trans-およびcis-エンジインの立体選択的合成

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Author (4)：

KONNO Tsutomu

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(Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN)

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KISHI Misato

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(Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN)

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ISHIHARA Takashi

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(Dep. of Chemistry and Materials Technol., Kyoto Inst. of Technol., Matsugasaki, Sakyo-ku, Kyoto 606-8585, JPN)

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YAMADA Shigeyuki

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(Dep. of Applied Chemistry, Graduate School of Engineering, Tokyo Univ. of Agriculture and Technol., 2-24-16 ...)

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Material：

Tetrahedron (Tetrahedron Symposia-in-Print)

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Volume： 70 Issue： 14 Page： 2455-2463 Publication year： Apr. 08, 2014
JST Material Number： E0234A ISSN： 0040-4020 Document type： Article
Article type：原著論文 Country of issue： United Kingdom (GBR) Language： ENGLISH (EN)

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metalation

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*organofluorine compound

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stereospecific reaction

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addition reaction

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enyne

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diyne

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organocopper compound

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stannanes

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organotin compound

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*Enediynes

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*carbocupration

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*hydrostannation

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JST classification (1)：

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Aliphatic halogen compounds

(CF03050P)

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Substance index (7)：

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(Z)-1-Phenyl-3-(trifluoromethyl)-4-butyl-7-methyl-7-(benzyloxy)-3-octene-1,5-diyne

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(Z)-2-Methyl-2-(benzyloxy)-5-butyl-6-(trifluoromethyl)-5-tetradecene-3,7-diyne

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(Z)-1-(Trimethylsilyl)-3-(trifluoromethyl)-4-butyl-7-methyl-7-(benzyloxy)-3-octene-1,5-diyne

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(E)-1-Phenyl-3-(trifluoromethyl)-7-methyl-7-(benzyloxy)-3-octene-1,5-diyne

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(Z)-2-Methyl-2-(benzyloxy)-6-(trifluoromethyl)-5-tetradecene-3,7-diyne

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(E)-1-(Trimethylsilyl)-3-(trifluoromethyl)-7-methyl-7-(benzyloxy)-3-octene-1,5-diyne

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(E)-1,6-Diphenyl-3-(trifluoromethyl)-3-hexene-1,5-diyne

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Terms in the title (6)：

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ジイン

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ヒドロスタンニル化

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置換

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CIS

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エンジイン

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立体選択的合成

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Stereoselective synthesis of CF3-substituted trans- and cis-enediynes via carbocupration or hydrostannation reactions of CF3-containing diyne

Stereoselective synthesis of CF₃-substituted trans- and cis-enediynes via carbocupration or hydrostannation reactions of CF₃-containing diyne