Art

J-GLOBAL ID：201402239363544660   Reference number：14A0571638

A Facile Preparation, Characteristic Properties, and Crystal Structure of {4-[(E)-2-(3-Guaiazulenyl)diazenyl]phenyl}(3-guaiazulenyl)methylium Hexafluorophosphate

{4-[(E)-2-(3-グアイアズレニル)ジアゼニル]フェニル}(3-グアイアズレニル)メチリウムヘキサフルオロホスファートの容易調製,特徴的性質,および結晶構造

Author (3)： TAKEKUMA Shin-ichi (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ.) ,  SEKI Atsuki (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ.) ,  MINEMATSU Toshie (School of Pharmaceutical Sciences, Kinki Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 87  Issue： 4  Page： 511-527 (J-STAGE)  Publication year： 2014 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： crystal structure ,  carbenium ion ,  fluorophosphate ,  Sodium tetrahydridoborate ,  pi electron ,  *cycloalkene ,  *polyene ,  alicyclic hydrocarbon ,  bicyclic sesquiterpene ,  Hexafluorophosphate ,  delocalization ,  *Azulenes
Semi thesaurus term： *Azulene derivatives ,  sodium borohydride

JST classification (1)： Condensed bicyclic carbocyclic compounds not containing 6-membered ring  (CF06050K)

Substance index (9)： Guaiazulene ,  4-[(E)-(3,8-Dimethyl-5-isopropylazulene-1-yl)azo]benzaldehyde ,  α-(3,8-Dimethyl-5-isopropylazulene-1-yl)-4-[(E)-(3,8-dimethyl-5-isopropylazulene-1-yl)azo]benzyl cation ,  1-[4-[(E)-(3,8-Dimethyl-5-isopropylazulene-1-yl)azo]benzyl]-3,8-dimethyl-5-isopropylazulene ,  Triphenyl(3,8-dimethyl-5-isopropyl-1-azulenylmethyl)phosphonium ,  4-[(E)-2-(3,8-Dimethyl-5-isopropylazulene-1-yl)vinyl]benzaldehyde ,  4-[(Z)-2-(3,8-Dimethyl-5-isopropylazulene-1-yl)vinyl]benzaldehyde ,  α-(3,8-Dimethyl-5-isopropylazulene-1-yl)-4-[(E)-2-(3,8-dimethyl-5-isopropylazulene-1-yl)vinyl]benzyl cation ,  1-[4-[(E)-2-(3,8-Dimethyl-5-isopropylazulene-1-yl)vinyl]benzyl]-3,8-dimethyl-5-isopropylazulene

Reference (46)：

• 1) S.-i. Takekuma, Y. Hata, T. Nishimoto, E. Nomura, M. Sasaki, T. Minematsu, H. Takekuma, Tetrahedron 2005, 61, 6892.
• 2) S.-i. Takekuma, K. Takahashi, A. Sakaguchi, Y. Shibata, M. Sasaki, T. Minematsu, H. Takekuma, Tetrahedron 2005, 61, 10349.
• 3) S.-i. Takekuma, K. Takahashi, A. Sakaguchi, M. Sasaki, T. Minematsu, H. Takekuma, Tetrahedron 2006, 62, 1520.
• 4) S.-i. Takekuma, M. Hirosawa, S. Morishita, M. Sasaki, T. Minematsu, H. Takekuma, Tetrahedron 2006, 62, 3732.
• 5) S.-i. Takekuma, K. Sonoda, C. Fukuhara, T. Minematsu, Tetrahedron 2007, 63, 2472.

Terms in the title (5)： フェニル ,  容易 ,  調製 ,  性質 ,  結晶構造