Art

J-GLOBAL ID：201502200640237820   Reference number：15A0895997

Palladium-Catalyzed Direct C-H Arylation of Isoxazoles at the 5-Position

5-位置におけるイソオキサゾール類のパラジウム触媒直接C-Hアリール化

Author (3)： SHIGENOBU Masashi (The Inst. of Scientific and Industrial Res. (ISIR), Osaka Univ., Mihogaoka, Ibaraki-shi, Osaka 567-0047 (Japan)) ,  TAKENAKA Kazuhiro (The Inst. of Scientific and Industrial Res. (ISIR), Osaka Univ., Mihogaoka, Ibaraki-shi, Osaka 567-0047 (Japan). ...) ,  SASAI Hiroaki (The Inst. of Scientific and Industrial Res. (ISIR), Osaka Univ., Mihogaoka, Ibaraki-shi, Osaka 567-0047 (Japan). ...)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 54  Issue： 33  Page： 9572-9576  Publication year： Aug. 10, 2015 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： arylation ,  chemical reaction ,  activation ,  palladium catalyst ,  palladium complex ,  catalytic reaction ,  *oxygen heterocyclic compound ,  *nitrogen heterocyclic compound ,  *aromatic iodine compound ,  *coupling reaction ,  reaction mechanism ,  spiro-compound ,  chiral ligand
Semi thesaurus term： C-H bond activation ,  *Isoxazoles ,  transition metal catalyzed reaction

JST classification (3)： Addition reaction,elimination reaction  (CF02030M) ,  Oxazoles,isoxazoles  (CF07080Y) ,  Aromatic monocyclic halogen compounds  (CF05030H)

Substance index (15)： 5-(p-Tolyl)-3,4-butanoisoxazole ,  3-(4-Fluorophenyl)-4,5,6,7-tetrahydro-2,1-benzoisoxazole ,  4,5,6,7-Tetrahydro-3-(4-chlorophenyl)-2,1-benzisoxazole ,  3-(4-Bromophenyl)-4,5,6,7-tetrahydro-2,1-benzoisoxazole ,  4,5,6,7-Tetrahydro-3-phenyl-2,1-benzisoxazole ,  4,5,6,7-Tetrahydro-3-(4-methoxyphenyl)-2,1-benzisoxazole ,  Benzoic acid (4,5,6,7-tetrahydro-2,1-benzoisoxazole-3-yl) ester ,  3-(1-Naphthyl)-4,5,6,7-tetrahydro-2,1-benzoisoxazole ,  3-(1-Pyrenyl)-4,5,6,7-tetrahydro-2,1-benzoisoxazole ,  3-(4-Chlorophenyl)-4-phenyl-5-(p-tolyl)isoxazole ,  3-(3-(4-Chlorophenyl)-5-(p-tolyl)isoxazole-4-yl)propionitrile ,  3-Methyl-5-(p-tolyl)isoxazole-4-carboxylic acid ethyl ester ,  3-(p-Tolyl)-2,1-benzoisoxazole ,  (7R,3′aS)-3-(1-Naphthyl)-3′,3′-diisopropyl-3′,3′aα,4,4′,5,5′-hexahydrospiro[2,1-benzoisoxazole-7(6H),6′-[6H]cyclopenta[c]isoxazole] ,  Benzoic acid (4,4-dimethyl-6α-isopropenyl-3-oxabicyclo[3.2.1]octane-1-yl)methyl ester

Terms in the title (3)： イソオキサゾール類 ,  パラジウム触媒 ,  アリール化