Art

J-GLOBAL ID：201502205247447572   Reference number：15A0953549

Addition Rate Constants of Phosphorus- and Carbon-Centered Radicals to Double Bond of Monomers as Studied by a Pulsed Electron Paramagnetic Resonance Method.

パルス電子常磁性共鳴法により研究した単量体二重結合へのリン/炭素中心ラジカルの付加速度定数

Author (5)： TAKAHASHI Hirona (Tokyo Inst. of Technol., Tokyo, JPN) ,  MARUSHIMA Yutaka (Tokyo Inst. of Technol., Tokyo, JPN) ,  TSUJI Kazuhide (Gunma Coll., Gunma, JPN) ,  SHIBUYA Kazuhiko (Tokyo Inst. of Technol., Tokyo, JPN) ,  KAWAI Akio (Tokyo Inst. of Technol., Tokyo, JPN)
Material： Journal of Physical Chemistry A  (Journal of Physical Chemistry A. Isolated Molecules, Clusters, Radicals, and Ions; Environmental Chemistry, Geochemistry, and Astrochemistry; Theory)
Volume： 119  Issue： 30  Page： 8261-8268  Publication year： Jul. 30, 2015 
JST Material Number： C0334B  ISSN： 1089-5639  CODEN： JPCAFH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *monomer ,  *double bond ,  *addition reaction ,  *constant ,  *phosphorus compound ,  *carbon compound ,  *radical ,  photopolymerization ,  initial stage ,  measurement ,  spectroscopy ,  ESR ,  intermediate ,  spectral analysis ,  spin echo ,  calculation ,  potential barrier ,  height ,  enthalpy ,  polarity ,  frequency(Hz) ,  *phosphine oxides ,  *photolysis/photodisintegration ,  lactam ,  organosilicon compound ,  carboxylate(ester)
Semi thesaurus term： pulse Electron Paramagnetic Resonance ,  activation barriers ,  time resolved method ,  initial stage ,  barrier height ,  *velocity constant ,  electron paramagnetic resonance spectroscopy ,  quantum chemical calculation

JST classification (6)： Organop phosphorus compounds  (CF08040N) ,  Organosilicon compounds  (CF08030C) ,  Photochemical reaction,radical reaction  (CF02090A) ,  Addition reaction,elimination reaction  (CF02030M) ,  EPR of organic compounds  (BM07024U) ,  Reaction kinetics and catalyst in general  (CB06010G)

Substance index (15)： Vinyltrimethoxysilane ,  Darocure TPO ,  IRG-184 ,  Irgacure 907 ,  α-Hydroxy-α-methylpropiophenone ,  Butyl vinyl ether ,  Ethyl vinyl ether ,  Methacrylic acid 3-(trimethoxysilyl)propyl ,  Methacrylic acid tert-butyl ,  Acrylic acid tert-butyl ,  α-Methylstyrene ,  1-Vinyl-2-pyrrolidone ,  N-Vinylcaprolactam ,  Diphenylphosphinyl radical ,  [3-(Diphenylphosphinyl)-1-tert-butoxy-1-oxopropane-2-yl]radical

Terms in the title (9)： パルス ,  電子常磁性共鳴法 ,  研究 ,  単量体 ,  二重結合 ,  リン ,  炭素 ,  ラジカル ,  速度定数