Art

J-GLOBAL ID：201502209445176105   Reference number：15A1219328

Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes

光レドックス触媒によるアルキン類の四置換トリフルオロメチル化アルケン類への立体選択的変換

Author (3)： TOMITA Ren (Chemical Resources Lab., Tokyo Inst. of Technol., R1-27, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan)) ,  KOIKE Takashi (Chemical Resources Lab., Tokyo Inst. of Technol., R1-27, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan). ...) ,  AKITA Munetaka (Chemical Resources Lab., Tokyo Inst. of Technol., R1-27, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan). ...)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 54  Issue： 44  Page： 12923-12927  Publication year： Oct. 26, 2015 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *alkene ,  alkyne ,  *aliphatic fluorine compound ,  photocatalytic reaction ,  *Alkylation ,  stereoselective reaction ,  chemical reaction ,  reaction mechanism ,  electrophilic reagent ,  transition metal catalyst ,  iridium complex ,  catalytic reaction ,  photoirradiation ,  palladium catalyst ,  palladium complex ,  cross coupling reaction ,  *addition reaction ,  iridium catalyst ,  *trifluoromethylation ,  regioselective reaction ,  visible light irradiation ,  photoredox catalysis
Semi thesaurus term： 光レドックス触媒 ,  photocatalysis

JST classification (2)： Alkenes  (CF03030T) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (15)： Trifluoromethanesulfonic acid (E)-1-phenyl-2-methyl-3,3,3-trifluoro-1-propenyl ester ,  (E)-1-(4-tert-Butylphenyl)-1-(trifluoromethylsulfonyloxy)-2-methyl-3,3,3-trifluoro-1-propene ,  Trifluoromethanesulfonic acid ((E)-1-(4-bromophenyl)-2-methyl-3,3,3-trifluoro-1-propenyl) ester ,  Trifluoromethanesulfonic acid ((E)-1-(4-methoxycarbonylphenyl)-2-methyl-3,3,3-trifluoro-1-propenyl) ester ,  Trifluoromethanesulfonic acid ((E)-1-(4-hydroxymethylphenyl)-2-methyl-3,3,3-trifluoro-1-propenyl) ester ,  Trifluoromethanesulfonic acid ((E)-1-(2-methyl-4-methoxycarbonylphenyl)-2-methyl-3,3,3-trifluoro-1-propenyl) ester ,  Trifluoromethanesulfonic acid ((E)-1-(4-chlorophenyl)-2-trifluoromethyl-1-butenyl) ester ,  (E)-2-Trifluoromethyl-3-phenyl-3-(trifluoromethanesulfonyloxy)acrylic acid methyl ester ,  Trifluoromethanesulfonic acid ((E)-1-phenyl-2-trifluoromethyl-3-oxo-1-butenyl) ester ,  Trifluoromethanesulfonic acid ((E)-1-(4-methoxyphenyl)-2-methyl-3,3,3-trifluoro-1-propenyl) ester ,  Trifluoromethanesulfonic acid ((E)-1-(4-acetylaminophenyl)-2-methyl-3,3,3-trifluoro-1-propenyl) ester ,  (E)-1-(4-Methoxyphenyl)-1-phenyl-2-methyl-3,3,3-trifluoro-1-propene ,  (1E,3Z)-1,3-Diphenyl-4-methyl-5,5,5-trifluoro-1,3-pentadiene ,  (E)-1-Phenyl-1-(3-thienyl)-2-methyl-3,3,3-trifluoro-1-propene ,  (E)-7-Phenyl-8-methyl-9,9,9-trifluoro-7-nonene-5-yne-1-ol

Terms in the title (5)： 光レドックス触媒 ,  置換 ,  トリフルオロメチル化 ,  アルケン ,  立体