Art

J-GLOBAL ID：201602289247004580   Reference number：16A1037008

Gold-catalyzed dehydrative Friedel-Crafts reaction and Nazarov cyclization sequence: an efficient synthesis of 1,3-diarylindenes from propargylic alcohols

金触媒による脱水Friedel-Crafts反応とNazarovシーケンス:プロパルギルアルコール類から1,3-ジアリールインデンの効率合成

Author (7)： Morita Nobuyoshi (Showa Pharmaceutical University, 3-3165 Higashi-Tamagawagakuen, Machida, Tokyo 194-8543, Japan) ,  Miyamoto Masazumi (Showa Pharmaceutical University, 3-3165 Higashi-Tamagawagakuen, Machida, Tokyo 194-8543, Japan) ,  Yoda Akiyoshi (Showa Pharmaceutical University, 3-3165 Higashi-Tamagawagakuen, Machida, Tokyo 194-8543, Japan) ,  Yamamoto Mari (Showa Pharmaceutical University, 3-3165 Higashi-Tamagawagakuen, Machida, Tokyo 194-8543, Japan) ,  Ban Shintaro (Showa Pharmaceutical University, 3-3165 Higashi-Tamagawagakuen, Machida, Tokyo 194-8543, Japan) ,  Hashimoto Yoshimitsu (Showa Pharmaceutical University, 3-3165 Higashi-Tamagawagakuen, Machida, Tokyo 194-8543, Japan) ,  Tamura Osamu (Showa Pharmaceutical University, 3-3165 Higashi-Tamagawagakuen, Machida, Tokyo 194-8543, Japan)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 57  Issue： 40  Page： 4460-4463  Publication year： Oct. 05, 2016 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： transition metal catalyst ,  catalytic reaction ,  *dewatering ,  *Friedel-Crafts reaction ,  *cyclization reaction ,  unsaturated alcohol ,  conjugated diene ,  allene compound ,  *Nazarov cyclization ,  *Indenes ,  *propargyl alcohols ,  *Au catalyst ,  alkylbenzene

Author keywords (5)： Gold catalyst ,  Dehydrative Friedel-Crafts reaction ,  Nazarov cyclization ,  13-Diarylindenes ,  Allenes

JST classification (2)： Indenes  (CF06030O) ,  Alkynes  (CF03040E)

Substance index (7)： Mesitylene ,  1,3-Diphenyl-2-propyn-1-ol ,  1-Phenyl-3-mesityl-1H-indene ,  1-Phenyl-3-(pentamethylphenyl)-1H-indene ,  1-Phenyl-3-(2,4,6-triisopropylphenyl)-1H-indene ,  2,4,6-Trimethyl-3-(3α-phenyl-3H-indene-1-yl)phenol ,  1β-Phenyl-3-(2,4,6-trimethyl-3-bromophenyl)-1H-indene

Terms in the title (5)： 金触媒 ,  脱水 ,  Friedel-Crafts反応 ,  シーケンス ,  プロパルギルアルコール類