Art

J-GLOBAL ID：201702214965080234   Reference number：17A1108887

Catalytic Asymmetric Intramolecular Cyclopropanation of α-Diazo-α-Silyl Acetate

α-ジアゾ-α-シリル酢酸エステルの接触的不斉分子内シクロプロパン化

Author (5)： INOUE Saori (Waseda Univ., Tokyo, JPN) ,  NAGATANI Kotaro (Waseda Univ., Tokyo, JPN) ,  TEZUKA Haruka (Waseda Univ., Tokyo, JPN) ,  HOSHINO Yunosuke (Waseda Univ., Tokyo, JPN) ,  NAKADA Masahisa (Waseda Univ., Tokyo, JPN)
Material： Synlett
Volume： 28  Issue： 9  Page： 1065-1070  Publication year： Jun. 01, 2017 
JST Material Number： W0113A  ISSN： 0936-5214  CODEN： SYNLES  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  catalytic reaction ,  copper catalyst ,  copper complex ,  ligand effect ,  *cyclization reaction ,  *lactone ,  carboxylate(ester) ,  *diazo compound ,  silanes ,  organosilicon compound ,  vinyl compound ,  alicyclic compound ,  enantiomer ,  reaction mechanism
Semi thesaurus term： *cyclopropanation ,  Cyclopropanes ,  Furans

JST classification (2)： Condensed derivatives of furan  (CF07073M) ,  Catalytic reactions in general  (CB06080F)

Substance index (11)： (1R,5α)-1α-(Trimethylsilyl)-6,6-dimethyl-3-oxabicyclo[3.1.0]hexane-2-one ,  (1S)-1α-(Trimethylsilyl)-5α-methyl-3-oxabicyclo[3.1.0]hexane-2-one ,  (5α)-1α-(Trimethylsilyl)-3-oxabicyclo[3.1.0]hexane-2-one ,  2,2′-(Pentane-3,3-diyl)bis(4β-isopropyl-2-oxazoline) ,  2,2′-(Dibenzylmethylene)bis(4β-isopropyl-2-oxazoline) ,  2,2′-Isopropylidenedi(2-oxazoline) ,  (S,S)-^tBubox ,  2,2′-Isopropylidenebis(4β-isopropyl-2-oxazoline) ,  Diazo(trimethylsilyl)acetic acid 2-methyl-2-propenyl ester ,  Diazo(trimethylsilyl)acetic acid 3-methyl-2-butenyl ester ,  Trimethylsilyldiazoacetic acid allyl ester

Terms in the title (2)： 酢酸エステル ,  シクロプロパン化