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J-GLOBAL ID：201702223368444275   Reference number：17A0658207

Photochemically Assisted Introduction of a Benzyl Unit into Isoquinolines Using Benzyltrifluoroborates

ベンジルトリフルオロボラートを用いるベンジル単位のイソキノリン類への光化学支援導入

Author (5)： Nishigaichi Yutaka (Department of Chemistry, Graduate School of Science and Engineering, Shimane University) ,  Orimi Takayuki (Department of Chemistry, Graduate School of Science and Engineering, Shimane University) ,  Koyachi Kuniyoshi (Department of Chemistry, Graduate School of Science and Engineering, Shimane University) ,  Ohmuro Yuuki (Department of Chemistry, Graduate School of Science and Engineering, Shimane University) ,  Suzuki Masaaki (Department of Chemistry, Graduate School of Science and Engineering, Shimane University)
Material： Chemistry Letters  (Chem Lett)
Volume： 45  Issue： 12  Page： 1382-1384(J-STAGE)  Publication year： 2016 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： fluoroborate ,  potassium compound ,  aromatic compound ,  *nitrogen heterocyclic compound ,  *polynuclear aromatic compound ,  *photochemical reaction ,  group(radical) ,  substituent effect ,  *benzylisoquinoline alkaloid ,  *benzylation
Semi thesaurus term： electron donating group ,  *Isoquinolines

Author keywords (3)： Isoquinoline alkaloid ,  Benzyltrifluoroborate ,  Photoirradiation

JST classification (3)： Quinolines,isoquinolines  (CF07096H) ,  Addition reaction,elimination reaction  (CF02030M) ,  Photochemical reactions  (CB08020F)

Substance index (5)： Isoquinoline ,  Chloroformic acid methyl ,  Potassium benzyltrifluoroborate ,  1-Benzylisoquinoline-2(1H)-carboxylic acid methyl ester ,  1-(4-Methoxybenzyl)-1,2-dihydroisoquinoline-2-carboxylic acid methyl ester

Reference (18)：

• 1) S. Darses, J.-P. Genel, Chem. Rev. 2008, 108, 288;
• 1) H. A. Stefani, R. Cella, A. S. Vieira, Tetrahedron 2007, 63, 3623.
• 2) G. A. Molander, J. Org. Chem. 2015, 80, 7837;
• 2) G. A. Molander, L. Jean-Gerard, Organic Reactions, Wiley, 2013, Vol. 79, p. 1. doi:10.1002/0471264180.or079.01.
• 3) R. A. Batey, A. N. Thadani, D. V. Smil, A. J. Lough, Synthesis 2000, 990.

Terms in the title (4)： ベンジル ,  イソキノリン類 ,  光化学 ,  支援