Art
J-GLOBAL ID：201702234309985781   Reference number：17A0271772

Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through the Primary Amine-Catalyzed Michael Addition Reaction of α-Substituted Cyclic Ketones at High Pressure

高圧下での一級アミン触媒を用いたα-置換環状ケトンのMichael付加反応による四級炭素立体中心のエナンチオ選択的合成
Author (8)：
HORINOUCHI Ryo

About HORINOUCHI Ryo

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN

, 
KAMEI Kouhei

About KAMEI Kouhei

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN

, 
WATANABE Riki

About WATANABE Riki

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN

, 
HIEDA Nobushige

About HIEDA Nobushige

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN

, 
TATSUMI Naoki

About TATSUMI Naoki

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN

, 
NAKANO Keiji

About NAKANO Keiji

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN

, 
ICHIKAWA Yoshiyasu

About ICHIKAWA Yoshiyasu

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN

, 
KOTSUKI Hiyoshizo

About KOTSUKI Hiyoshizo

(Kochi Univ., Kochi, JPN)

About Kochi Univ., Kochi, JPN


Material：
European Journal of Organic Chemistry  (Eur J Org Chem)

About European Journal of Organic Chemistry


Volume： 2015  Issue： 20  Page： 4457-4463  Publication year： Jul. 2015 
JST Material Number： W1026A  ISSN： 1434-193X  CODEN： EJOCFK  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)
Thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
catalytic reaction

About catalytic reaction

, 
*asymmetric reaction

About asymmetric reaction

, 
chemical reaction

About chemical reaction

, 
*Michael reaction

About Michael reaction

, 
carboxylate(ester)

About carboxylate(ester)

, 
*alicyclic ketone

About alicyclic ketone

, 
total synthesis

About total synthesis

, 
unsaturated fatty acid

About unsaturated fatty acid

, 
vinyl compound

About vinyl compound

, 
aliphatic nitrile

About aliphatic nitrile


Semi thesaurus term：
Thesaurus term/Semi thesaurus term
Keywords indexed to the article.
All keywords is available on JDreamIII(charged).
On J-GLOBAL, this item will be available after more than half a year after the record posted. In addtion, medical articles require to login to MyJ-GLOBAL.
*acrylate

About acrylate

, 
*High-Pressure reaction

About High-Pressure reaction

, 
*asymmetric organocatalysis

About asymmetric organocatalysis


JST classification (2)：
JST classification
Category name(code) classified by JST.
Aliphatic ketones 
(CF03190Q)

About Aliphatic ketones

,  Addition reaction,elimination reaction 
(CF02030M)

About Addition reaction,elimination reaction

Substance index (7)：
Substance index
Chemical Substance indexed to the Article.
Aspidospermidine

About Aspidospermidine

, 
2-Methylcyclohexanone

About 2-Methylcyclohexanone

, 
Acrylic acid methyl

About Acrylic acid methyl

, 
Acrylonitrile

About Acrylonitrile

, 
(1R)-1-Methyl-2-oxocyclohexanepropiononitrile

About (1R)-1-Methyl-2-oxocyclohexanepropiononitrile

, 
3-[(1R)-1-Methyl-2-oxocyclopentyl]propanoic acid methyl ester

About 3-[(1R)-1-Methyl-2-oxocyclopentyl]propanoic acid methyl ester

, 
(R)-1-Methyl-2-oxocyclohexanepropanoic acid methyl ester

About (R)-1-Methyl-2-oxocyclohexanepropanoic acid methyl ester

Terms in the title (8)：
Terms in the title
Keywords automatically extracted from the title.
高圧

About 高圧

, 
アミン触媒

About アミン触媒

, 
置換

About 置換

, 
環状ケトン

About 環状ケトン

, 
Michael付加反応

About Michael付加反応

, 
炭素

About 炭素

, 
立体中心

About 立体中心

, 
エナンチオ選択的合成

About エナンチオ選択的合成


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