Art

J-GLOBAL ID：201702247184962734   Reference number：17A0509709

Thiyl radical-mediated cyclization of ω-alkynyl O-tert-butyldiphenylsilyloximes

ω-アルキニルO-tert-ブチルジフェニルシリルオキシム類のチイルラジカル媒介環化反応

Author (6)： Shibata Nina (Showa Pharmaceutical University, 3-3165, Higashi-Tamagawagakuen, Machida, Tokyo, Japan. [e-mail]) ,  Tsuchiya Takahisa ,  Hashimoto Yoshimitsu ,  Morita Nobuyoshi ,  Ban Shintaro ,  Tamura Osamu
Material： Organic & Biomolecular Chemistry  (Org Biomol Chem)
Volume： 15  Issue： 14  Page： 3025-3034  Publication year： 2017 
JST Material Number： A0499C  ISSN： 1477-0520  CODEN： OBCRAK  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical reaction ,  *cyclization reaction ,  thiol ,  radical ,  *radical reaction ,  addition reaction ,  *hydroxylamine ,  nitrone ,  reaction mechanism ,  nitrogen heterocyclic compound ,  oxygen heterocyclic compound ,  transition state ,  elimination reaction ,  thiyl radical ,  *free-radical cyclization ,  radical addition ,  desilylation ,  azo compound ,  aliphatic nitrile
Semi thesaurus term： desilylation

JST classification (2)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Aliphatic hydroxylamines,hydrazines and other polynitrogen compounds  (CF03080W)

Substance index (17)： 4-tert-Butylbenzenethiol ,  AIBN ,  N-(Benzyloxy)-2-(4-(tert-butyl)phenylthiomethylene)cyclopentane-1-amine ,  N-(tert-Butyldiphenylsiloxy)-2-(4-(tert-butyl)phenylthiomethylene)cyclopentane-1-amine ,  N-(Benzyloxy)-4-(4-(tert-butyl)phenylthiomethylene)tetrahydrofuran-3-amine ,  N-(tert-Butyldiphenylsiloxy)-4-(4-(tert-butyl)phenylthiomethylene)tetrahydrofuran-3-amine ,  N-(tert-Butyldiphenylsiloxy)-1-tosyl-3-(4-(tert-butyl)phenylthiomethylene)pyrrolidine-5-amine ,  N-(tert-Butyldiphenylsiloxy)-2-(1-(4-(tert-butyl)phenylthio)ethylidene)cyclopentane-1-amine ,  N-(tert-Butyldiphenylsiloxy)-1-tosyl-3-(2-(4-(tert-butyl)phenylthio)ethylidene)pyrrolidine-5-amine ,  N-(tert-Butyldiphenylsiloxy)-1-methyl-2-(4-(tert-butyl)phenylthiomethylene)cyclopentane-1-amine ,  N-(tert-Butyldiphenylsiloxy)-2-methyl-3-(4-(tert-butyl)phenylthio)-2-cyclohexene-1-amine ,  N-(tert-Butyldiphenylsiloxy)-4-methyl-5-(4-(tert-butyl)phenylthio)-1,2,3,6-tetrahydropyridine-3-amine ,  N-(tert-Butyldiphenylsiloxy)-2-phenyl-3-(4-(tert-butyl)phenylthio)-2-cyclohexene-1-amine ,  N-(tert-Butyldiphenylsiloxy)-4-phenyl-5-(4-(tert-butyl)phenylthio)-1,2,3,6-tetrahydropyridine-3-amine ,  N-(Benzyloxy)-4-(4-(tert-butyl)phenylthiomethylene)tetrahydro-2H-pyran-3-amine ,  N-(tert-Butyldiphenylsiloxy)-4-(4-(tert-butyl)phenylthiomethylene)tetrahydro-2H-pyran-3-amine ,  N-(tert-Butyldiphenylsiloxy)-4-(4-(tert-butyl)phenylthiomethylene)piperidine-3-amine

Terms in the title (3)： TERT ,  チイルラジカル ,  環化反応